azane;dibromopalladium;tetrabromoiridium | 364060-33-3

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物
• 英文名称: azane;dibromopalladium;tetrabromoiridium
• CAS: 364060-33-3
• 化学式: Br₆Ir*H₁₂N₄Pd
• 分子量: 846.186
• InChiKey: SXYVPJSIWNIJPB-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  5.72
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  azane;dibromopalladium;tetrabromoiridium 以 neat (no solvent, solid phase) 为溶剂， 生成 palladium iridium
  参考文献：
  名称：

  摘要：

  The complex salt [Pd(NH3)(4)][IrBr6] was synthesized and studied using X-ray powder diffraction, thermal and elemental analyses, and IR and Raman spectroscopy methods. Crystallographic parameters: a = 11.999 Angstrom, b = 11.290 Angstrom, c = 10.802 Angstrom, V = 1463.3 Angstrom (3), Z = 4, space group Cmca, rho (calcd) = 3.841 g/cm(3). Thermolysis in an inert atmosphere runs through four stages to yield an equiatomic Pd-Ir solid solution as the final product.

  DOI：

  10.1023/a:1011393700721
• 作为产物：
  描述：

  tetramminepalladium(II) chloride 、 potassium hexabromoiridate(IV) 以 水 为溶剂， 以92%的产率得到azane;dibromopalladium;tetrabromoiridium
  参考文献：
  名称：

  摘要：

  The complex salt [Pd(NH3)(4)][IrBr6] was synthesized and studied using X-ray powder diffraction, thermal and elemental analyses, and IR and Raman spectroscopy methods. Crystallographic parameters: a = 11.999 Angstrom, b = 11.290 Angstrom, c = 10.802 Angstrom, V = 1463.3 Angstrom (3), Z = 4, space group Cmca, rho (calcd) = 3.841 g/cm(3). Thermolysis in an inert atmosphere runs through four stages to yield an equiatomic Pd-Ir solid solution as the final product.

  DOI：

  10.1023/a:1011393700721