(croconato)manganese(II)(bipyridyl)*H2O | 128844-20-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: (croconato)manganese(II)(bipyridyl)*H2O
• CAS: 128844-20-2
• 化学式: C₁₅H₈MnN₂O₅*H₂O
• 分子量: 369.192
• InChiKey: JQQHOYWEHSWIAQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.89
• 重原子数：
  24.0
• 可旋转键数：
  1.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  154.61
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 manganese(II) chloride tetrahydrate 、 dipotassium croconate 以 乙醇 为溶剂， 生成 (croconato)manganese(II)(bipyridyl)*H2O
  参考文献：
  名称：

  Deguenon, Diane; Bernardinelli, Gérald; Tuchagues, Jean-Pierre, Inorganic Chemistry, 1990, vol. 29, # 16, p. 3031 - 3037

  摘要：

  DOI：

文献信息

• Poly[[[aqua(2,2′-bipyridine-κ²<i>N</i>,<i>N</i>′)manganese(II)]-μ-croconato-κ⁴<i>O</i>,<i>O</i>′:<i>O</i>′′,<i>O</i>′′′] monohydrate]: a one-dimensional coordination polymer connected by hydrophilic–hydrophilic and lipophilic–lipophilic interactions at 135 K
  作者：Hong-Feng Chen、Qi Fang、Hong-Yu Chen、Wen-Tao Yu、Lin-Hong Weng

  DOI：10.1107/s0108270110006979

  日期：2010.4.15

  In the title one-dimensional coordination polymer, [Mn(C5O5)(C10H8N2)(H2O)]center dot H2O}n, each Mn-II ion is sevencoordinated by four O atoms from two croconate ligands, two N atoms from a 2,2'-bipyridine (2,2'-bipy) ligand and one O atom from an aqua ligand. The croconate ligand bridges the Mn-II ions in a bis-bidentate chelation mode, forming an extended [Mn(C5O5)] n chain running parallel to the [001] direction, with the lipophilic 2,2'-bipy ligands lying along one side and the hydrophilic water molecules along the opposite side. Coordinated water and solvent water molecules are arranged in the hydrophilic layer, which is characterized by O-H center dot center dot center dot O hydrogen bonds between croconate ligands. Meanwhile, 2,2'-bipy ligands from adjacent chains partially overlap and exhibit pi-pi interactions to form a lipophilic layer. The hydrophilic and lipophilic layers are arranged alternately to build a layer structure.