Solid-phase room-temperature decomposition of a complex salt trans-[Rh(γ-Pic)4Cl2]MnO4
摘要:
Permanganate salt of the complex cation trans-[Rh(gamma-Pic)(4)Cl-2](+) (gamma-Pic = gamma-picoline) was synthesized. The unusual decomposition reaction of the salt was studied at room temperature. This process has been found to conserve the gamma-picoline ligands in cation untouched. A number of transformations in anionic part of salt have been observed. Metallic products of the salt thermal decomposition have been studied. (C) 2011 Elsevier Ltd. All rights reserved.