[Et3NH][(2-Cl-C6H4CH2)2SnCl2(2-quinaldic acid(-1H))] | 849144-33-8

• 英文名称: [Et3NH][(2-Cl-C6H4CH2)2SnCl2(2-quinaldic acid(-1H))]
• CAS: 849144-33-8
• 化学式: C₆H₁₆N*C₂₄H₁₈Cl₄NO₂Sn
• 分子量: 715.134
• InChiKey: SRKWYYSPHOMCDX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  喹哪啶酸 、 二氯双[(2-氯苯基)甲基]锡烷 、 三乙胺 以 二氯甲烷 为溶剂， 以78%的产率得到[Et3NH][(2-Cl-C6H4CH2)2SnCl2(2-quinaldic acid(-1H))]
  参考文献：
  名称：

  Synthesis and characterization of ionic organotin compounds [R2SnCl2(2-quin)]−(HNEt3)+ and crystal structures of [(2,4-Cl2-C6H3CH2)2SnCl2(2-quin)]−(HNEt3)+

  摘要：

  Eight ionic organotin compounds [R2SnCl2(2-quin)](-)(HNEt3)(+) have been synthesized by reactions of 2-quinH with R2SnCl2 (R = PhCH2 1, 2-Cl-C6H4CH2 2, 4-Cl-C6H4CH2 3, 2-F-C6H4CH2 4, 4-F-C6H4CH2 5, 4-CN-C6H4CH2 6, Ph 7, 2,4-Cl-2-C6H3CH2 8) in the presence of organic base NEt3, and their structures have been characterized by elemental analysis, IR and multinuclear NMR (H-1 C-13, Sn-119) spectroscopies. The structure of [(2,4-Cl-2-C6H3CH2)(2)SnCl2(2-quin)](-)(NEt3)(+) (8) has been determined by X-ray diffraction study. Studies show that compound 8 has a monomeric structure with the central tin atom six-coordinate in a distorted octahedral configuration and the nitrogen atoms of the 2-quin ligands are coordinating to the tin atom in all the eight compounds. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.11.003