trans-[Os(MeTe(CH2)3TeMe)2Cl2] | 267008-47-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: trans-[Os(MeTe(CH2)3TeMe)2Cl2]
• 英文别名: 1,3-bis(methyltellanyl)propane;dichloroosmium
• CAS: 267008-47-9
• 化学式: C₁₀H₂₄Cl₂OsTe₄
• 分子量: 915.807
• InChiKey: SYHZVOMDYYNANR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,3-bis(methyltelluro)propane 、 trans-[osmium(II)Cl2(dimethyl sulfoxide-S)4] 以 甲醇 为溶剂， 以36%的产率得到trans-[Os(MeTe(CH2)3TeMe)2Cl2]
  参考文献：
  名称：

  Synthesis and properties of ditelluroether complexes of osmium, trans-[OsCl2(L-L)2] and trans-[OsCl(PPh3)(L-L)2]PF6 (L-L=o-C6H4(TeMe)2, RTe(CH2)3TeR (R=Ph or Me))

  摘要：

  The complexes trans-[OsCl2(L-L)(2)] (L-L=o-C6H4(TeMe)(2), RTe(CH2)(3)TeR (R = Ph or Me)) have been prepared from trans-[OsCl2(dmso)(4)] and the ditelluroethers in ethanol. The reaction of [OsCl2(PPh3)(3)] with the ditelluroethers or MeSCH2CH2SMe or MeSe(CH2)(3)SeMe in ethanol in the presence of NH4PF6 gave trans-[OsCl(PPh3) (L-L)(2)]PF6. The complexes have been characterised by analysis, IR, UV-Vis and multinuclear NMR spectroscopy. The reaction of OsO4-HCl-EtOH with PhTe(CH2)(3)TePh results in chlorination of the ligand to PhTeCl2(CH2)(3)TePhCl2, identified by single-crystal X-ray study. The X-ray structure for trans-[OsCl2{PhTe(CH2)(3)TePh}(2)] is reported. The reaction of [OsCl2(dmso)(4)] with the distibine Ph2Sb(CH2)(3)SbPh2 affords trans-[OsCl2{Ph2Sb(CH2)(3)SbPh2}(2)] which has also been characterised crystallographically. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00376-9