Allyl-ethyl-phosphinsaeure-allylester | 14656-01-0

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: Allyl-ethyl-phosphinsaeure-allylester
• 英文别名: ethyl-allyl-phosphinic acid allyl ester；Aethyl-allyl-phosphinsaeure-allylester；3-[Ethyl(prop-2-enyl)phosphoryl]oxyprop-1-ene
• CAS: 14656-01-0
• 化学式: C₈H₁₅O₂P
• 分子量: 174.18
• InChiKey: PBYPTCCIXKGMEK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  Diallyloxy-ethyl-phosphin 以 萘烷 为溶剂， 生成 Allyl-ethyl-phosphinsaeure-allylester
  参考文献：
  名称：

  Pudovik,A.I. et al., Journal of general chemistry of the USSR, 1967, vol. 37, p. 656 - 661

  摘要：

  DOI：

文献信息

• FLAME RETARDANT FILLERS PREPARED FROM BRIDGED POLYSILSESQUIOXANES
  申请人：Boday Dylan J.

  公开号：US20140041908A1

  公开（公告）日：2014-02-13

  A bridged polysilsesquioxane-based flame retardant filler imparts flame retardancy to manufactured articles such as printed circuit boards (PCBs), connectors, and other articles of manufacture that employ thermosetting plastics or thermoplastics. In an exemplary synthetic method, a bridged polysilsesquioxane-based flame retardant filler is prepared by sol-gel polymerization of a monomer having two or more trialkoxysilyl groups attached to an organic bridging group that contains a fire retardant group (e.g., a halogen atom, a phosphinate, a phosphonate, a phosphate ester, and combinations thereof). Bridged polysilsesquioxane particles formed by sol-gel polymerization of (((2,5-dibromo-1,4-phenylene)bis(oxy))bis(ethane-2,1-diyl))bis(trimethoxysilane), for example, and follow-on sol-gel processing may serve both as a filler for rheology control (viscosity, flow, etc.) and a flame retardant. In an exemplary application, a PCB laminate stack-up includes conductive planes separated from each other by a dielectric material that includes a bridged polysilsesquioxane-based flame retardant filler.
• ARTICLE OF MANUFACTURE CONTAINING A FLAME RETARDANT FILLER PREPARED FROM A BRIDGED POLYSILSESQUIOXANE
  申请人：International Business Machines Corporation

  公开号：US20160137842A1

  公开（公告）日：2016-05-19

  A bridged polysilsesquioxane-based flame retardant filler imparts flame retardancy to manufactured articles such as connectors and other articles of manufacture that employ thermosetting plastics or thermoplastics. In an exemplary synthetic method, a bridged polysilsesquioxane-based flame retardant filler is prepared by sol-gel polymerization of a monomer having two or more trialkoxysilyl groups attached to an organic bridging group that contains a fire retardant group (e.g., a halogen atom, a phosphinate, a phosphonate, a phosphate ester, and combinations thereof). Bridged polysilsesquioxane particles formed by sol-gel polymerization of (((2,5-dibromo-1,4-phenylene)bis(oxy))bis(ethane-2,1-diyl))bis(tri-methoxysilane), for example, and follow-on sol-gel processing may serve both as a filler for rheology control (viscosity, flow, etc.) and a flame retardant.
• ELECTRONIC CIRCUIT BOARD CONTAINING A FLAME RETARDANT FILLER PREPARED FROM A BRIDGED POLYSILSESQUIOXANE
  申请人：International Business Machines Corporation

  公开号：US20160143136A1

  公开（公告）日：2016-05-19

  A bridged polysilsesquioxane-based flame retardant filler imparts flame retardancy to printed circuit boards (PCBs). In an exemplary synthetic method, a bridged polysilsesquioxane-based flame retardant filler is prepared by sol-gel polymerization of a monomer having two or more trialkoxysilyl groups attached to an organic bridging group that contains a fire retardant group (e.g., a halogen atom, a phosphinate, a phosphonate, a phosphate ester, and combinations thereof). Bridged polysilsesquioxane particles formed by sol-gel polymerization of (((2,5-dibromo-1,4-phenylene)bis(oxy))bis(ethane-2,1-diyl))bis(trimethoxysilane), for example, and follow-on sol-gel processing may serve both as a filler for rheology control (viscosity, flow, etc.) and a flame retardant. In an embodiment of the present invention, a PCB laminate stack-up includes conductive planes separated from each other by a dielectric material that includes a bridged polysilsesquioxane-based flame retardant filler.
• US4257987A
  申请人：——

  公开号：US4257987A

  公开（公告）日：1981-03-24
• US9255185B2
  申请人：——

  公开号：US9255185B2

  公开（公告）日：2016-02-09