4,6-dipyridinio-2-oxido-1,3,5-triazine chloride | 4772-15-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 4,6-dipyridinio-2-oxido-1,3,5-triazine chloride
• 英文别名: 1,1'-(hydroxy-[1,3,5]triazine-2,4-diyl)-bis-pyridinium betaine; chloride；1,1'-(Hydroxy-[1,3,5]triazin-2,4-diyl)-bis-pyridinium-betain; Chlorid；4,6-di(pyridin-1-ium-1-yl)-1,3,5-triazin-2-olate;chloride
• CAS: 4772-15-0
• 化学式: C₁₃H₁₀N₅O*Cl
• 分子量: 287.708
• InChiKey: DBYZAXXQSLNOTR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -3.5
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  69.5
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2,4,6-tripyridinio-1,3,5-triazine trichloride 在 水 作用下， 反应 0.25h， 以35%的产率得到4,6-dipyridinio-2-oxido-1,3,5-triazine chloride
  参考文献：
  名称：

  2,4,6-Tripyridino-1,3,5-triazine Trichloride, a New and Mild Esterification Agent for Preparation of Penicillin Esters

  摘要：

  Cyanuric chloride reacted with 3 molar equivalents of pyridine to give 2,4,6-tripyridinio-1,3,5-triazine trichloride, which was found to condense penicillins with alcohols under mild conditions to afford penicillin esters in good yields. Application to preparation of cephalosporin esters also is discussed.

  DOI：

  10.3987/com-90-5565

文献信息

• A Promising 1,3,5-Triazine-Based Anion Exchanger for Perrhenate Binding: Crystal Structures of Its Chloride, Nitrate and Perrhenate Salts
  作者：Valery N. Zakharov、Pavel S. Lemport、Vladimir V. Chernyshev、Victor A. Tafeenko、Alexandr V. Yatsenko、Yuri A. Ustynyuk、Sergey F. Dunaev、Valentine G. Nenajdenko、Leonid A. Aslanov

  DOI：10.3390/molecules28041941

  日期：——

  The reaction of pyridine with cyanuric chloride was studied under microwave activation as well as in the presence of silver nitrate. The product of hydrolysis containing two pyridinium rings and chloride anion was isolated. The structures of these anion exchanger salts with chloride, nitrate and perrhenate anions are discussed.

  研究了在微波活化以及硝酸银存在下吡啶与氰尿酰氯的反应。分离出含有两个吡啶鎓环和氯阴离子的水解产物。讨论了这些带有氯离子、硝酸根和高铼酸根阴离子的阴离子交换盐的结构。
• Tsujikawa, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1965, vol. 85, p. 846,849
  作者：Tsujikawa

  DOI：——

  日期：——
• Saure, Chemische Berichte, 1950, vol. 83, p. 335,339, 340
  作者：Saure

  DOI：——

  日期：——
• MURAKAMI, MASAYUKI;HAJIMA, MAKOTO;TAKAMI, FUMITAKA;YOSHIOKA, MITSURU, HETEROCYCLES, 31,(1990) N, C. 2055-2064
  作者：MURAKAMI, MASAYUKI、HAJIMA, MAKOTO、TAKAMI, FUMITAKA、YOSHIOKA, MITSURU

  DOI：——

  日期：——