N-butyl-N'-cyclohexyl-[1,3,5]triazine-2,4,6-triamine | 47003-03-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: N-butyl-N'-cyclohexyl-[1,3,5]triazine-2,4,6-triamine
• 英文别名: 4-N-butyl-2-N-cyclohexyl-1,3,5-triazine-2,4,6-triamine
• CAS: 47003-03-2
• 化学式: C₁₃H₂₄N₆
• 分子量: 264.374
• InChiKey: RNQCCTIMLQMIAC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  88.8
• 氢给体数：
  3
• 氢受体数：
  6

文献信息

• Proton-conducting polymer
  申请人：Nippon Steel Chemical Co., Ltd.

  公开号：EP2562864A1

  公开（公告）日：2013-02-27

  The present invention provides a proton conducting polymer which provides proton conductivity without humidification and is suitable for electrochemical device materials such as solid electrolytes for fuel cells and electrolytes for batteries. The proton conducting compound is produced by polymerization of a salt of a melamine compound represented by the following equation (2) and a Bronsted acid: wherein, R1, R2, R3, R4, and R5 each is independently an alkyl group, an aryl group, a heterocyclic group, or hydrogen and at least one of them is an alkyl group, an aryl group, or a heterocyclic group; R2 and R3 or R4 and R5 may join together to form a heterocyclic structure; and the alkyl group, the aryl group, and the heterocyclic group each may have a substituent selected from the group of alkyl groups of 1 to 6 carbon atoms, aryl groups of 6 to 12 carbon atoms, heterocyclic groups, an amino group, alkylamino groups of 1 to 6 carbon atoms, a nitro group, a carboxyl group, acryl groups of 1 to 6 carbon atoms, acyloxy groups of 1 two 6 carbon atoms, a cyano group, alkylsulfonyl groups of 1 to 6 carbon atoms, alkylsulfonyloxy groups of 1 to 6 carbon atoms, a sulfoxide group, a sulfonic acid group, alkoxycarbonyl groups of 1 to 6 carbon atoms, aryloxycarbonyl groups of 6 to 12 carbon atoms, aryloxy groups of 6 to 12 carbon atoms, and alkynyl groups of 2 to 6 carbon atoms; R6 is hydrogen or an alkyl group and n is an integer equal to or larger than 1,

  本发明提供了一种质子传导聚合物，无需加湿即可提供质子传导性，适用于电化学装置材料，如燃料电池的固体电解质和电池的电解质。质子导电化合物是由下式（2）表示的三聚氰胺化合物的盐和勃朗斯特酸聚合而成： 其中，R1、R2、R3、R4 和 R5 各自独立地为烷基、芳基、杂环基或氢，且其中至少一个为烷基、芳基或杂环基；R2 和 R3 或 R4 和 R5 可连接在一起形成杂环结构；烷基、芳基和杂环基各自可具有一个取代基，该取代基可选自以下基团：1 至 6 个碳原子的烷基、6 至 12 个碳原子的芳基、杂环基、氨基、1 至 6 个碳原子的烷基氨基、硝基、羧基、1 至 6 个碳原子的丙烯基、1-6个碳原子的酰氧基、氰基、1-6个碳原子的烷磺酰基、1-6个碳原子的烷磺酰氧基、亚砜基、磺酸基、1-6个碳原子的烷氧羰基、6-12个碳原子的芳氧羰基、6-12个碳原子的芳氧基和 2-6个碳原子的炔基；R6 是氢或烷基，n 是等于或大于 1 的整数、