Bis--quecksilber | 10507-39-8

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Bis--quecksilber
• 英文别名: bis(methoxycarbonyl)mercury
• CAS: 10507-39-8
• 化学式: C₄H₆HgO₄
• 分子量: 318.679
• InChiKey: LORCGGMKAPNOSW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  三苯基膦铂 、 Bis--quecksilber 以 苯 为溶剂， 以92%的产率得到trans-[(Ph3P)2Pt(CO2CH3)2]
  参考文献：
  名称：

  Synthesis of ester and amide derivatives of platinum and palladium metalcarboxylic acids by the organomercury method

  摘要：

  DOI：

  10.1007/bf01168280

文献信息

• Exploring the coordinative behaviour and molecular architecture of new PhHg(II)/Hg(II) dithiocarbamate complexes
  作者：Manoj K. Yadav、Gunjan Rajput、Ajit N. Gupta、Vinod Kumar、Michael G.B. Drew、Nanhai Singh

  DOI：10.1016/j.ica.2014.05.031

  日期：2014.9
• Synthesis of methyl trimethylsilanecarboxylate. The n .far. .pi.* transition of silanecarboxylates
  作者：Garry J. D. Peddle、R. W. Walsingham

  DOI：10.1021/ja01036a075

  日期：1969.4
• Conversion of Lactose into Mimics ofN-Acetyllactosamine
  作者：Luigi Lay、Laura Cipolla、Barbara La Ferla、Francesco Peri、Francesco Nicotra

  DOI：10.1002/(sici)1099-0690(199912)1999:12<3437::aid-ejoc3437>3.0.co;2-0

  日期：1999.12

  The alpha-C-Glycoside of N-acetyllactosamine 8 was synthesised from lactose by acetylation, conversion into the allyl alpha-C-glycoside 4, exchanging the protecting groups for benzyl ethers, selective deprotection at the gluco-C-2 by iodocyclisation-reductive elimination, and conversion of the free hydroxyl group into an acetamido group by oxidation, oximation, stereoselective reduction and acetylation. Isomerization of the C-glycosidic appendage by conversion into a 2-oxypropyl group and treatment with base gave, after acetylation, the beta-C-glycoside of N-acetyllactosamine 11.