| 380376-07-8

• 分子结构分类: 有机化合物 - 有机磷化合物
• CAS: 380376-07-8；544671-55-8
• 化学式: C₁₇H₃₆AgO₂P
• 分子量: 411.314
• InChiKey: WOVJNIKJPDJESW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三丁基膦 、 特戊酸银 以 四氯化碳 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Synthesis and crystal structure of silver(I) carboxylate complexes, Ag(PnBu3)[C(CH3)3COO] and Ag(Phen)2[CF3COO]·H2O

  摘要：

  Ag((PBu3)-Bu-n)[C(CH3)(3)COO] (I) and Ag(Phen)(2)[CF3COO]-H2O (II) were synthesized by the reaction of silver (I) carboxylate with the neutral ligand in absolute ether and ethanol, respectively. Crystal structures of I and II were determined by single crystal X-ray diffraction. The crystal structure of I is built up from dimeric units in which two Ag((PBU3)-B-n)[C(CH3)(3)COO] molecules are linked by two Ag-O bonds (2.626 Angstrom). The closest coordination environment of the silver atom consists of two oxygen atoms with average Ag-O distances of 2.38 Angstrom and one phosphorous atom with a Ag-P distance of 2.326 Angstrom. The crystal structure of II is formed by infinite rows of [Ag(Phen)(2)](+) cations between which [CF3COO](-) anions are arranged. Relations between volatility and crystal structures of I and II are discussed. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00011-1

文献信息

• Malkerova; Paramonov; Alikhanyan, Russian Journal of Inorganic Chemistry, 2001, vol. 46, # 10, p. 1544 - 1546
  作者：Malkerova、Paramonov、Alikhanyan、Kuz'mina

  DOI：——

  日期：——