| 148482-26-2

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 148482-26-2
• 化学式: C₆H₁₄Cl₂N₂O₂W
• 分子量: 400.945
• InChiKey: RKFNQRMHTMWLHQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,4-二甲基哌嗪 、 dichloro(1,2-dimethoxyethane)dioxotungsten(VI) 以 二氯甲烷 为溶剂， 以42%的产率得到
  参考文献：
  名称：

  Complexes of MoO2Cl2 and WO2Cl2 with the ligands N,N,N′,N′-tetramethylethylenediamine, N,N′-di-t-butyl-1,4-diaza-1,3-butadiene and N,N′-dimethylpiperazine. cis,trans,cis vs all cis coordination in bidentate N-donor complexes of WO2Cl2 and MoO2Cl2. Crystal structures of MoO2Cl2(N,N,N′,N′-tetramethylethylenediamine) and MoO2Cl2(N,N′-DI-t-butyl-1,4-diaza-1,3-butadiene)

  摘要：

  The complexes [MoO2Cl2(But-dab)], [WO2Cl2(But-dab)] (But-dab = N,N'-di-t-butyl-1,4-diaza-1,3-butadiene), [MoO2Cl2(dmp)] and [WO2Cl(dmp)] (dmp = N,N'-dimethylpiperazine) have been prepared and characterized by IR, Raman, H-1 and C-13 NMR spectroscopy. [MO2Cl2(dmp)] (M = Mo, W) has cis-dichloroligands and [MoO2Cl2(dmp)] shows fluxional behaviour of the coordinated ligand in CH2Cl2 solution, as monitored by H-1 NMR spectroscopy. The structures of [MoO2Cl2(tmen)] (tmen= N,N,N',N'-tetramethylethylenediamine) and [MoO2Cl2(But-dab)] are reported. Both compounds are built up of discrete molecules with distorted octahedral geometry and cis-dioxoligands, the former having the unusual cis-dichloro and the latter the common trans-dichloro arrangement. MoO2Cl2(tmen) has Mo=O distances of 1.681(4) and 1.697(4) angstrom with an O-Mo-O angle of 103.1(2)-degrees. The trans influence of the oxo-ligands is shown by two different Mo-Cl distances [2.449(2) angstrom trans to O and 2.338(2) angstrom trans to N] and two different Mo-N distances [2.464(4) angstrom trans to O and 2.278(4) angstrom trans to Cl]. MoO2Cl2(But-dab) has an Mo=O distance of 1.688(3) and an O-Mo-O angle of 104.5(2)degrees. The trans-dichloro ligands have equal distances to molybdenum, d(Mo-Cl) = 2.356(1) angstrom. The Mo-N distances of the nitrogen atoms trans to the oxo groups are 2.399(2) and 2.388(2) angstrom.

  DOI：

  10.1016/s0277-5387(00)81728-3