N-[[[tert-butyl(trimethylstannyl)amino]-dimethylsilyl]oxy-dimethylsilyl]-2-methyl-N-trimethylstannylpropan-2-amine | 146748-65-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: N-[[[tert-butyl(trimethylstannyl)amino]-dimethylsilyl]oxy-dimethylsilyl]-2-methyl-N-trimethylstannylpropan-2-amine
• CAS: 146748-65-4
• 化学式: C₁₈H₄₈N₂OSi₂Sn₂
• 分子量: 602.183
• InChiKey: NYLAXEACMGRTRY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.28
• 重原子数：
  25.0
• 可旋转键数：
  6.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  15.71
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  N-[[[tert-butyl(trimethylstannyl)amino]-dimethylsilyl]oxy-dimethylsilyl]-2-methyl-N-trimethylstannylpropan-2-amine 、 copper(l) chloride 以 正己烷 为溶剂， 以42%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of silazoxy metallacycles

  摘要：

  Novel transition-metal-containing metallacycles of the type [{M[O(SiMe2NBut)2]}2] (M = Mn(II) 2, Fe(II) 3, Ni(II) 4 or Cr(II) 5) as well as six-membered heterocycles of the type O(SiMe2NBUt)2M (M = Te(II) 8, Ge(II) 9 or Sn(II) 10) have been synthesised by the reaction of O(SiMe2NButLi)2 with the corresponding metal halides. Reaction of CuCl2 and CuCl with O(SiMe2NButLi)2 yielded a novel copper amide [Cu4{O(SiMe2NBUt)2}2] 7 having four copper atoms in a square plane bridged symmetrically from above and below by the diamide ligand. This compound was also prepared by the reaction of O[SiMe2N(But)SnMe3], with CuCl2 and CuCl. X-Ray crystallographic data obtained are as follows: 2, triclinic, space group P1BAR, a = 8.550(2), b = 9.838(2), c = 11.668(2) angstrom, alpha = 83.81(3), beta = 70.35(3), gamma = 72.55(3)-degrees, Z = 1; 3, triclinic, space group P1BAR, a = 11.201(5), b = 11.579(4), c = 14.946(9) angstrom, alpha 1 06.90 (3), beta = 97.59 (2), gamma = 1 0 1 . 27 (2)-degrees, Z = 2.

  DOI：

  10.1039/dt9930000495
• 作为产物：
  描述：

  Dilithium;tert-butyl-[[tert-butylazanidyl(dimethyl)silyl]oxy-dimethylsilyl]azanide 、 三甲基氯化锡 以75%的产率得到
  参考文献：
  名称：

  Elias Anil J., Roesky Herbert W., Robinson Ward T., Sheldrick George M., J. Chem. Soc. Dalton Trans, (1993) N 4, S 495-500

  摘要：

  DOI：