diisopropoxy((trimethylstannyl)oxy)aluminum | 138977-00-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: diisopropoxy((trimethylstannyl)oxy)aluminum
• CAS: 138977-00-1
• 化学式: C₉H₂₃AlO₃Sn
• 分子量: 324.971
• InChiKey: PALVFZCQVCGYSS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.67
• 重原子数：
  14.0
• 可旋转键数：
  6.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.69
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  diisopropoxy((trimethylstannyl)oxy)aluminum 、 1-苯基-1,3-丁二酮 以 苯 为溶剂， 生成 {Me3SnOAl(benzoylacetonate)2}
  参考文献：
  名称：

  Some new organotin(IV), aluminium(III)-μ-oxoisopropoxides and their benzoylacetone derivatives

  摘要：

  The first organotin(IV), alummium(III)-mu-oxoisopropoxides of the type [R3SnOAl(O(i)Pr)2] (R = Me or Ph) have been made by heating of trimethyl- or triphenyl-tin acetate with aluminium isopropoxide. The reactions of these mu-oxoisopropoxides with benzoylacetone in 1:1 and 1:2 molar ratios yielded the compounds of the type [R3SnOAl(O(i)Pr)(bzac)] and [R3SnOAl(bzac)2] (where R = Me or Ph and bzac = deprotonated benzoylacetone), respectively.

  DOI：

  10.1016/0022-328x(91)86459-4
• 作为产物：
  描述：

  aluminum isopropoxide 、 乙酸三甲基锡 以 甲苯 为溶剂， 以95%的产率得到diisopropoxy((trimethylstannyl)oxy)aluminum
  参考文献：
  名称：

  Some new organotin(IV), aluminium(III)-μ-oxoisopropoxides and their benzoylacetone derivatives

  摘要：

  The first organotin(IV), alummium(III)-mu-oxoisopropoxides of the type [R3SnOAl(O(i)Pr)2] (R = Me or Ph) have been made by heating of trimethyl- or triphenyl-tin acetate with aluminium isopropoxide. The reactions of these mu-oxoisopropoxides with benzoylacetone in 1:1 and 1:2 molar ratios yielded the compounds of the type [R3SnOAl(O(i)Pr)(bzac)] and [R3SnOAl(bzac)2] (where R = Me or Ph and bzac = deprotonated benzoylacetone), respectively.

  DOI：

  10.1016/0022-328x(91)86459-4