[(η5-C5Me5)Ru(μ2-(i)PrNC(Me)=N(i)Pr)Ru(η5-C5Me5)]SbF6 | 401918-49-8

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: [(η5-C5Me5)Ru(μ2-(i)PrNC(Me)=N(i)Pr)Ru(η5-C5Me5)]SbF6
• 英文别名: hexafluoroantimony(1-);(C-methyl-N-propan-2-ylcarbonimidoyl)-propan-2-ylazanide;1,2,3,4,5-pentamethylcyclopenta-1,3-diene;ruthenium(2+)
• CAS: 401918-49-8
• 化学式: C₂₈H₄₇N₂Ru₂*F₆Sb
• 分子量: 849.575
• InChiKey: PZXOBSKMSFWPCJ-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  silver hexafluoroantimonate 、 (η5-C5Me5)Ru(μ2-(i)PrN=C(Me)N(i)Pr)Ru(Br)(η5-C5Me5) 以 二氯甲烷 为溶剂， 以93%的产率得到[(η5-C5Me5)Ru(μ2-(i)PrNC(Me)=N(i)Pr)Ru(η5-C5Me5)]SbF6
  参考文献：
  名称：

  Novel Coordinatively Unsaturated Bimetallic Complexes, [(η⁵-C₅Me₅)Ru(μ₂-ⁱPrNC(Me)NⁱPr)Ru(η⁵-C₅Me₅)]⁺:  A Bridging Amidinate Ligand Perpendicular to the Metal−Metal Axis Effectively Stabilizes the Highly Reactive Cationic Diruthenium Species

  摘要：

  Coordinatively unsaturated diruthenium complexes, [(eta5-C5Me5)Ru(mu2-iPrNC(Me)=NiPr)Ru(eta5-C5Me5)]+, of which crystallography revealed structures bearing a bridging amidinate ligand perpendicular to the Ru-Ru axis, were synthesized by anion exchange of [(eta5-C3Me5(Ru(mu2-iPrNC(Me)=NiPr)Ru(eta5-C5Me5)]+ Br- by weakly coordinating anions. Variable-temperature NMR showed rapid motion of the bridging amidinate ligand. The coordinatively unsaturated nature of the cationic complexes provides their high reactivity toward a series of two electron donor ligands. Oxidative addition of molecular hydrogen occurred to give [(eta5-C5Me5)Ru(mu2-iPrNC(Me)=NiPr)(mu-H)Ru(eta5-C5Me5)(H)]+, which was isolated and characterized.

  DOI：

  10.1021/ja016899h