| 258280-78-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• CAS: 258280-78-3；260994-47-6；192046-77-8
• 化学式: C₁₀H₂₀N₈Ni₂*H₂O
• 分子量: 387.718
• InChiKey: FNDRRGIGNFUJBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium tetracyanidonickellate(II) monohydrate 、 nickel(II) chloride hexahydrate 、 1,2-丙二胺 以 水 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  The design, assembly, properties and crystal structure of one-dimensional polymeric cyanide-bridged nickel(II)/nickel(II) complexes

  摘要：

  Four novel one-dimensional polymeric complexes {[Ni(pn)(2)Ni(CN4]. H2O}(n) (1), {[Ni(tn)(2)Ni(CN)(4)]. H2O}(n) (2), {[Ni(dien)Ni(CN)(4)] (H2O)(2))}(n) (3) and {[Ni(trien)Ni(CN)(4)]. H2O}(n) (4) (where pn = 1,2-diaminopropane, tn = 1,3-diaminopropane, dien = diethylenetriamine and trien = triethylenetetraamine) have been synthesized by the reaction of [Ni(L)(m)](2+) with [Ni(CN)(4)](2-) in aqueous solution. Their properties have been studied by IR spectra, UV-Vis spectra, cyclic voltammetry and variable temperature magnetic susceptibility measurements. The molecular structure of complex I has been determined by X-ray diffraction, consisting of a one-dimensional polymeric chain -Ni(pn)(2)-NC-Ni(CN)(2)-CN-Ni(pn)(2)- in which the N(II) centers are linked by two CN groups. The formation of cyanide bridges is evident from the IR and W-Vis spectra by appearance of nu(CN) shifts and changes in lambda(max) with respect to the mononuclear parent complex [Ni(CN)(4)](2-). (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00411-9