| 12600-43-0

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• CAS: 12600-43-0
• 化学式: InO₂
• 分子量: 146.819
• InChiKey: PQTRHBKVFPSNFI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.62
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  indium(III) oxide 以 gaseous matrix 为溶剂， 生成 、 、 、 、
  参考文献：
  名称：

  脉冲激光蒸发的镓和铟原子与分子氧的反应：新的二氧化镓和二氧化铟物种的基质红外光谱

  摘要：

  Infrared spectra were obtained in solid argon at 12 +/- 1 K for gallium and indium oxides produced from the reaction of laser-ablated metal atoms with molecular oxygen. Several new molecules were characterized including bent species GaO2' at 568.7 cm-1 and InO2' at 462.4 cm-1, which were distinctly different from previously observed cyclic MO2 species, linear metal atom insertion products OGaO at 912.7 cm-1 and OInO at 755.4 cm-1, and linear GaOGaO at 967-959 cm-1 and InOInO at 816.6 cm-1. The linear insertion products increased on mercury arc photolysis suggesting that metal atom electronic excitation-can provide the activation energy necessary for the insertion reaction. Also observed were the suboxides MOM, the M+O3- ozonide species, and the OMOMO trioxide species. The same absorptions were produced with different relative intensities by ablation of solid M2O3 oxide samples.

  DOI：

  10.1021/j100204a019