[copper(II)(N-benzyl-N,N-bis(6-methyl-2-pyridylmethyl)amine)(O-benzoyl-salicylate)] perchlorate | 911143-20-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [copper(II)(N-benzyl-N,N-bis(6-methyl-2-pyridylmethyl)amine)(O-benzoyl-salicylate)] perchlorate
• 英文别名: Cu(II)(Bn-6Me2)(O-bs) perchlorate
• CAS: 911143-20-9
• 化学式: C₃₅H₃₂ClCuN₃O₈
• 分子量: 721.653
• InChiKey: SFAQIYUQELYHAQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 2-苯甲酰氧基苯甲酸 、 N,N-bis(6-methylpyridin-2-ylmethyl)benzylamine 在 N(C₂H₅)3 作用下， 以 甲醇 为溶剂， 以55%的产率得到[copper(II)(N-benzyl-N,N-bis(6-methyl-2-pyridylmethyl)amine)(O-benzoyl-salicylate)] perchlorate
  参考文献：
  名称：

  (O-Benzoylsalicylato)copper(II) complexes as synthetic enzyme-product models for flavonol 2,4-dioxygenase

  摘要：

  Mononuclear complexes of the type [Cu-II(BPEA)(O-bs)], [Cu-II(BnBPA)(O-bs)]ClO4, and [Cu-II(Bn-6Me(2)BPA)(O-bs)]ClO4 [O-bsH = O-benzoylsalicylic acid, BPEAH = N,N-bis(2-pyridylmethyl)amino-2-ethanoic acid, BnBPA = N-benzyl-N,N-bis(2-pyridylmethyl)amine, Bn-6Me(2)BPA = N-benzyl-N,N-bis(6-methyl-2-pyridylmethyl)amine] were synthesized as synthetic enzyme-depside complexes, and characterized by spectroscopic measurements and X-ray crystal analysis. The oxygenation of flavonol using the above-mentioned complexes as catalyst results in the oxidative cleavage of the heterocyclic ring to give a O-benzoylsalicylic acid and CO as a mimic of quercetinase action. (C) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.11.011