phosphorous acid tris(2,2,6,6-tetramethyl piperidin-4-yl ester) | 24820-38-0

• 分子结构分类: 有机化合物 - 有机磷化合物 - 亚磷酸三烷基酯
• 英文名称: phosphorous acid tris(2,2,6,6-tetramethyl piperidin-4-yl ester)
• 英文别名: Tris(2,2,6,6-tetramethylpiperidin-4-yl) phosphite
• CAS: 24820-38-0
• 化学式: C₂₇H₅₄N₃O₃P
• 分子量: 499.718
• InChiKey: MILPIQHBMVLAAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  34
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  63.8
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  phosphorous acid tris(2,2,6,6-tetramethyl piperidin-4-yl ester) 生成 Phosphoric acid tris-(2,2,6,6-tetramethyl-piperidin-4-yl) ester
  参考文献：
  名称：

  KONIG, T.;HABICHER, W. D.;SCHWETLICK, K., J. PRAKT. CHEM., 331,(1989) N, C. 913-922

  摘要：

  DOI：
• 作为产物：
  描述：

  di(2,2,6,6-tetra-methyl-piperidin-4-oxy)-(diethylamino)phosphine 在 水 作用下， 反应 1.0h， 以57.1%的产率得到phosphorous acid bis(2,2,6,6-tetramethyl piperidin-4-yl ester)
  参考文献：
  名称：

  含有位阻哌啶基团的新型有机亚磷酸酯的合成

  摘要：

  摘要 描述了几种具有位阻哌啶基团的亚磷酸酯的合成，这些亚磷酸酯是合成聚合物的潜在稳定剂。亚磷酸六乙基三酰胺 (1) 与 4-羟基哌啶化合物 2 和 3 以 1:1 和 1:2 的比例反应，分别得到亚磷酸单酯二酰胺 4 和 5 以及亚磷酸二酯单酰胺 6 和 7。这些化合物可以选择性地水解为亚磷酸二酯 8 和 9 以及亚磷酸单酯 14 和 15。新的亚磷酸酯酰胺 4、5、6 和 7 是合成具有位阻哌啶的亚磷酸酯的有用结构单元部分。描述了这类化合物的几个代表。

  DOI：

  10.1080/10426509708031565

文献信息

• Alpha-Hydroxy-beta-2,2,6,6-tetramethyl piperidyl ethylene oxiranes as light and heat stabilizers for polyvinyl chloride resins
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0213484A1

  公开（公告）日：1987-03-11

  α-Hydroxy-β-2,2,6,6-tetramethyl piperidyl ethylene oxiranes are provided, capable of improving the resistance to deterioration when exposed to light and heat of polyvinyl chloride resins, and having the general formula: as well as polyvinyl chloride resin compositions containing , such stabilizers.

  本发明提供了α-羟基-β-2,2,6,6-四甲基哌啶乙烯环氧乙烷，能够提高聚氯乙烯树脂在光和热条件下的抗变质能力，其通式如下： 以及含有这种稳定剂的聚氯乙烯树脂组合物。
• SOLAR BATTERY SEALING MATERIAL
  申请人：Du Pont-Mitsui Polychemicals Co., Ltd.

  公开号：EP1990840A1

  公开（公告）日：2008-11-12

  The present invention provides an encapsulating material for a solar cell, which is easy to prepare a solar cell module, and excellent in processability, insulating property, non-corrosion property, transparency, heat resistance, flexibility and the like, anda solar cell module prepared by using the same. The encapsulating material for a solar cell is one consisting of a cross-linkable resin composition (A) containing an ethylene- (meth) acrylic ester copolymer as a base polymer, an organic peroxide and a crosslinking aid wherein the decomposition temperature (temperature for a half-life period of one hour) of the organic peroxide is equal to or lower than 150°C, and total compounding amount of the organic peroxide and the crosslinking aid ,is in a range of from 0.5 to 5 parts by weight per 100 parts by weight of the base polymer, and compounding ratio of the organic peroxide and the crosslinking aid (organic peroxide/ crosslinking aid) is in a range of from 1/5 to 1/0.1, in weight ratio.

  本发明提供了一种太阳能电池封装材料，它易于制备太阳能电池组件，并且在加工性、绝缘性、非腐蚀性、透明性、耐热性、柔韧性等方面性能优良，还提供了用其制备的太阳能电池组件。用于太阳能电池的封装材料由可交联树脂组合物 (A) 组成，该组合物含有作为基础聚合物的乙烯-（甲基）丙烯酸酯共聚物、有机过氧化物和交联助剂，其中有机过氧化物的分解温度（半衰期为一小时的温度）等于或低于 150°C，有机过氧化物和交联助剂的总复合量范围为每 100 个太阳能电池组件中 0.有机过氧化物和交联助剂(有机过氧化物/交联助剂)的混合物总量的重量比范围为每 100 重量份基础聚合物 0.5 至 5 重量份，有机过氧化物和交联助剂(有机过氧化物/交联助剂)的混合物重量比范围为 1/5 至 1/0.1。
• KONIG, T.;HABICHER, W. D.;SCHWETLICK, K., J. PRAKT. CHEM., 331,(1989) N, C. 913-922
  作者：KONIG, T.、HABICHER, W. D.、SCHWETLICK, K.

  DOI：——

  日期：——
• RESIN COMPOSITION FOR BIODEGRADABLE AGRICULTURAL FILMS WITH ENHANCED WEATHERABILITY
  申请人：C.I. Kasei Co., Ltd.

  公开号：EP1173507A1

  公开（公告）日：2002-01-23
• ENCAPSULATING MATERIAL FOR SOLAR CELL
  申请人：Nishijima Koichi

  公开号：US20100229944A1

  公开（公告）日：2010-09-16

  The present invention provides an encapsulating material for a solar cell, which is easy to prepare a solar cell module, and excellent in processability, insulating property, non-corrosion property, transparency, heat resistance, flexibility and the like, and a solar cell module prepared by using the same. The encapsulating material for a solar cell is one consisting of a cross-linkable resin composition (A) containing an ethylene-(meth)acrylic ester copolymer as a base polymer, an organic peroxide and a crosslinking aid wherein the decomposition temperature (temperature for a half-life period of one hour) of the organic peroxide is equal to or lower than 150° C., and total compounding amount of the organic peroxide and the crosslinking aid, is in a range of from 0.5 to 5 parts by weight per 100 parts by weight of the base polymer, and compounding ratio of the organic peroxide and the crosslinking aid (organic peroxide/crosslinking aid) is in a range of from 1/5 to 1/0.1, in weight ratio.