Methyl tert-butyldithiocarbamate | 152507-46-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 二硫代氨基甲酸及其衍生物
• 英文名称: Methyl tert-butyldithiocarbamate
• 英文别名: methyl N-t-butyldithiocarbamate；methyl N-tert-butylcarbamodithioate
• CAS: 152507-46-5
• 化学式: C₆H₁₃NS₂
• 分子量: 163.308
• InChiKey: CPIVYMPRRCHNLU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  69.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Methyl tert-butyldithiocarbamate 、 DL-丙氨酸 在 三乙胺 作用下， 以 乙醇 为溶剂， 反应 5.0h， 以78%的产率得到3-Tert-butyl-5-methyl-2-sulfanylideneimidazolidin-4-one
  参考文献：
  名称：

  Reactivity of Dithiocarbamic Esters: Methods for the Preparation of 3,5-Substituted 2-Thiohydantoins

  摘要：

  DOI：

  10.1055/s-1983-30349
• 作为产物：
  描述：

  异氰酸叔丁酯 在 N,N-二甲基硫代甲酰胺 、 异氰酸叔丁酯 作用下， 以 四氢呋喃 为溶剂， 反应 15.0h， 生成 Methyl tert-butyldithiocarbamate
  参考文献：
  名称：

  Three-component cyclocondensations. Two methods for the efficient preparation of 5-aminothiazolium salts via the reaction of isocyanides either with dimethylthioformamide and imino chloro sulfides or benzaldimines and aryl chlorothioformates

  摘要：

  Treatment of imino chloro sulfides with dimethylthioformamide and isocyanides at room temperature provides selectively the 5-amino-4-(dimethylamino)-2-(methylthio)(or phenylthio)thiazolium salts. Similarly, the reactions of p-tolyl chlorothionoformate and phenyl chlorodithioformate with a mixture of benzaldimine and isocyanide afford rapidly the 5-amino-4-phenylthiazolium salts. We suggest that these reactions involve the N-(thiocarbonyl)formamidinium and benzylideniminium chlorides as transient intermediates, which are trapped by isocyanides according to a [1 + 4] cycloaddition process. The structure of the thiazolium salts and some of their reactivities are discussed.

  DOI：

  10.1021/jo00074a032

文献信息

• BLOTNY, G., SYNTHESIS, BRD, 1983, N 5, 39
  作者：BLOTNY, G.

  DOI：——

  日期：——
• FUNCTIONALIZED SILANES AND ELECTROLYTE COMPOSITIONS AND ELECTROCHEMICAL DEVICES CONTAINING THEM
  申请人：Silatronix, Inc.

  公开号：US20170301953A1

  公开（公告）日：2017-10-19

  Described are compounds of the structure R4— a —Si—(Sp-Y) a —Z b , wherein “a” is integer from 1 to 4; “b” is an integer from 0 to (3×a); “Z,” which is absent when “b”“R” or formula (II), wherein each “R” is halogen, C 1-6 linear or branched alkyl, alkenyl, or alkynyl or C 1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl; each “Sp” C 1-15 linear or branched alkylenyl or CMS linear or branched halo-alkylenyl; and each “Y” an organic polar group. Also described are electrolyte compositions containing one or more of these compounds.