di-tert-butyl(bis(trimethylsilyl)amido)indium(III) | 152581-40-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: di-tert-butyl(bis(trimethylsilyl)amido)indium(III)
• CAS: 152581-40-3
• 化学式: C₁₄H₃₆InNSi₂
• 分子量: 389.438
• InChiKey: WETTXDMDLLVDRT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.55
• 重原子数：
  18.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  bis(μ-chloro)tetra-tert-butyldiindium(III) 、 sodium hexamethyldisilazane 以 乙醚 为溶剂， 以30%的产率得到di-tert-butyl(bis(trimethylsilyl)amido)indium(III)
  参考文献：
  名称：

  Synthesis and characterization of new monomeric dialkylindium amides

  摘要：

  A series of organoindium amido compounds have been prepared for use as dopants in the organometallic vapor phase epitaxy (OMVPE) of II-VI semiconductor materials. Thus, reaction of tBu2InCl or iPr2InCl with the appropriate lithium or sodium dialkyiamide afforded compounds of the type R2InNR2' (where R = (t)Bu, (i)Pr, and R' = Me, (i)Pr, SiMe3). Similarly, reaction of the N-lithiated derivative of NCMe2(CH2)3CMe2 gave iPr2InNCMe2(CH)3CMe2. All of the compounds are monomeric liquids, except for the compound where R = (t)Bu, R' = Me, which is a dimeric solid. The compounds have been characterized by H-1 and C-13 NMR, IR, molecular weight determination, and elemental analysis. In addition, properties relevant to the OMVPE process such as volatility and photosensitivity are presented and evaluated.

  DOI：

  10.1016/0022-328x(93)83312-j