5-(Dimethylamino)-2-[(2-hydroxyphenyl)diazenyl]phenol | 50783-83-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 5-(Dimethylamino)-2-[(2-hydroxyphenyl)diazenyl]phenol
• CAS: 50783-83-0
• 化学式: C₁₄H₁₅N₃O₂
• 分子量: 257.292
• InChiKey: OUCGULSJNFCJDX-UHFFFAOYSA-N

物化性质

• 沸点：
  481.9±45.0 °C(Predicted)
• 密度：
  1.20±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  68.4
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  5-(Dimethylamino)-2-[(2-hydroxyphenyl)diazenyl]phenol 、 chromium(III) acetate hydroxide 在 sodium carbonate 作用下， 以 乙醇 为溶剂， 生成 C₂₈H₂₆CrN₆O₄
  参考文献：
  名称：

  The Synthesis and Characterizations of Thermally-Stable Yellow Metal Complex Dyes for LCD Color Filters

  摘要：

  Eight kinds of yellow metal (III) complex azo dyes were synthesized using different diazo component, coupling component and metal ion. The effect on the thermal stability of the synthesized dyes by azo ligand with two different functional groups, alcohol and carboxylic acid, was studied. The characteristics of the synthesized dyes were examined by their absorption maxima, thermal stability by a thermogravimetric analysis (TGA), and the chromatic characteristics of the fabricated films were measured. It was also explained that the effect of functional groups on the thermal stability of the dyes as well as their chromaticity values.

  DOI：

  10.1080/15421406.2013.844883
• 作为产物：
  描述：

  2-氨基苯酚 、 3-羟基-N,N-二甲基苯胺 在 盐酸 、 sodium nitrite 、 sodium hydroxide 作用下， 以 水 为溶剂， 反应 10.5h， 生成 5-(Dimethylamino)-2-[(2-hydroxyphenyl)diazenyl]phenol
  参考文献：
  名称：

  The Synthesis and Characterizations of Thermally-Stable Yellow Metal Complex Dyes for LCD Color Filters

  摘要：

  Eight kinds of yellow metal (III) complex azo dyes were synthesized using different diazo component, coupling component and metal ion. The effect on the thermal stability of the synthesized dyes by azo ligand with two different functional groups, alcohol and carboxylic acid, was studied. The characteristics of the synthesized dyes were examined by their absorption maxima, thermal stability by a thermogravimetric analysis (TGA), and the chromatic characteristics of the fabricated films were measured. It was also explained that the effect of functional groups on the thermal stability of the dyes as well as their chromaticity values.

  DOI：

  10.1080/15421406.2013.844883