| 115587-21-8

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 115587-21-8
• 化学式: C₈H₁₂I₂N₄Ti*I₃
• 分子量: 846.613
• InChiKey: ZMSWVFTWIZXCNX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 以210 %的产率得到碘化钛(IV)
  参考文献：
  名称：

  Troyanov, S. I.; Mazo, G. N., Russian Journal of Inorganic Chemistry, 1988, vol. 33, p. 499 - 501

  摘要：

  DOI：
• 作为产物：
  描述：

  碘化钛(IV) 、 乙腈 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Troyanov, S. I.; Mazo, G. N., Russian Journal of Inorganic Chemistry, 1988, vol. 33, p. 499 - 501

  摘要：

  DOI：

文献信息

• The use of trimethylsilyl iodide as a synthon in coordination chemistry
  作者：G.Jeffery Leigh、J.Roger Sanders、Peter B. Hitchcock、Jaisa Soares Fernandes、Maria Togrou

  DOI：10.1016/s0020-1693(01)00801-5

  日期：2002.3

  Trimethylsilyl iodide is shown to be an efficient metathetical reagent for preparing transition-metal iodides from the corresponding chlorides. though often complications can cause problems. These include reduction of the starting metal chloride when its oxidation state is high, due to the reaction of iodide, and even oxidation of low-oxidation-state compounds, presumably by incipient silyl cations. Finally, some very inert chlorides, such as of iridium(III), react too slowly with the iodide under the experimental conditions, and simple reaction with solvent becomes predominant. (C) 2002 Elsevier Science B.V. All rights reserved.