2,2'-(6-(dimethylamino)-1,3,5-triazine-2,4-diyl)bis(methyl-azanediyl)bis(methylene)diphenol | 1307264-10-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2,2'-(6-(dimethylamino)-1,3,5-triazine-2,4-diyl)bis(methyl-azanediyl)bis(methylene)diphenol
• 英文别名: 2-[[[4-(Dimethylamino)-6-[(2-hydroxyphenyl)methyl-methylamino]-1,3,5-triazin-2-yl]-methylamino]methyl]phenol；2-[[[4-(dimethylamino)-6-[(2-hydroxyphenyl)methyl-methylamino]-1,3,5-triazin-2-yl]-methylamino]methyl]phenol
• CAS: 1307264-10-3
• 化学式: C₂₁H₂₆N₆O₂
• 分子量: 394.476
• InChiKey: QVMJKYQAFFUGDA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  29
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  88.8
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2,4-bis[(hydroxymethyl)methylamino]-6-dimethylamino-1,3,5-triazine 、 苯酚 在 甲酸 聚合甲醛 作用下， 以 水 为溶剂， 反应 6.0h， 生成 2,4'-(6-(dimethylamino)-1,3,5-triazine-2,4-diyl)bis(methyl-azanediyl)bis(methylene)diphenol 、 4,4'-(6-(dimethylamino)-1,3,5-triazine-2,4-diyl)bis(methyl-azanediyl)bis(methylene)diphenol 、 2,2'-(6-(dimethylamino)-1,3,5-triazine-2,4-diyl)bis(methyl-azanediyl)bis(methylene)diphenol
  参考文献：
  名称：

  [EN] MELAMINE BASED MANNICH-COMPOUNDS AND A PROCESS FOR OBTAINING THE SAME
  [FR] COMPOSÉS DE MANNICH À BASE DE MÉLAMINE ET PROCÉDÉ POUR OBTENIR CEUX-CI

  摘要：

  本发明涉及通式（1）-（12）的基于三聚氰胺的Mannich化合物以及一种合成基于三聚氰胺的Mannich产物的方法，该方法包括以下步骤：a）在碱性条件下将至少一种取代三聚氰胺与至少一种醛反应，特别是甲醛，形成至少一种含有羟基的化合物；b）在催化剂的存在下将至少一种含有羟基的化合物与至少一种Mannich碱反应；c）将至少一种Mannich碱与至少一种生成烯醇的羰基化合物反应，或c2）将至少一种Mannich碱与至少一种芳香化合物反应；d）处理反应混合物。该发明还涉及从这些产物中获得的预缩聚物。

  公开号：

  WO2011061220A1

文献信息

• Melamine Based Mannich-Compounds and a Process for Obtaining the Same
  申请人：Dicke René

  公开号：US20120277429A1

  公开（公告）日：2012-11-01

  The present invention relates to Melamine based Mannich compounds of the general formulae (1)-(12) and a process for synthesizing melamine based Mannich-products comprising the steps of a) reacting at least one substituted melamine with at least one aldehyde, in particular formaldehyde, under basic conditions to form at least one OH-containing compound, b) reacting the at least one OH-containing compound in the presence of a catalyst to form at least one mannich-base, c1) reacting the at least one mannich-base with at least one enol-forming carbonyl compound, or c2) reacting the at least one mannich-base with at least one aromatic compound, and d) working up the reaction mixture. The invention relates further to precondensates obtainable from these products.
• US8802848B2
  申请人：——

  公开号：US8802848B2

  公开（公告）日：2014-08-12
• [EN] MELAMINE BASED MANNICH-COMPOUNDS AND A PROCESS FOR OBTAINING THE SAME<br/>[FR] COMPOSÉS DE MANNICH À BASE DE MÉLAMINE ET PROCÉDÉ POUR OBTENIR CEUX-CI
  申请人：BOREALIS AGROLINZ MELAMINE

  公开号：WO2011061220A1

  公开（公告）日：2011-05-26

  The present invention relates to Melamine based Mannich compounds of the general formulae (1 )-(12) and a process for synthesizing melamine based Mannich-products products comprising the steps of a) reacting at least one substituted melamine with at least one aldehyde, in particular formaldehyde, under basic conditions to form at least one OH-containing compound, b) reacting the at least one OH-containing compound in the presence of a catalysts to form at least one mannich-base, d ) reacting the at least one mannich-base with at least one enol-forming carbonyl compound, or c2) reacting the at least one mannich-base with at least one aromatic compound, and d) working up the reaction mixture. The invention relates further to pre-condensates obtainable from these products.

  本发明涉及通式（1）-（12）的基于三聚氰胺的Mannich化合物以及一种合成基于三聚氰胺的Mannich产物的方法，该方法包括以下步骤：a）在碱性条件下将至少一种取代三聚氰胺与至少一种醛反应，特别是甲醛，形成至少一种含有羟基的化合物；b）在催化剂的存在下将至少一种含有羟基的化合物与至少一种Mannich碱反应；c）将至少一种Mannich碱与至少一种生成烯醇的羰基化合物反应，或c2）将至少一种Mannich碱与至少一种芳香化合物反应；d）处理反应混合物。该发明还涉及从这些产物中获得的预缩聚物。