| 1421069-83-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• CAS: 1421069-83-1
• 化学式: C₈₈H₆₆O₁₁Si₂
• 分子量: 1355.66
• InChiKey: LINCNYONGJYAQJ-MNFLEDGVSA-N

反应信息

• 作为产物：
  描述：

  三乙基硅烷 、 在 三(五氟苯基)硼烷 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 以30%的产率得到
  参考文献：
  名称：

  Synthesis of C₆₀(O)₃: An Open-Cage Fullerene with a Ketolactone Moiety on the Orifice

  摘要：

  Four isomers are currently known for the trioxygenated fullerene derivative C-60(O)(3), three regioisomers with all of the oxygen addends as epoxy groups and the unstable ozonide isomer with a 1,2,3-trioxlane ring. Here we report the synthesis of an open-cage isomer for C-60(O)(3) with a ketolactone moiety embedded into the fullerene skeleton through a three-step procedure mediated by fullerene peroxide chemistry. Two fullerene skeleton carbon-carbon bonds are cleaved in the process. The open-cage derivative C-60(O)(3) can be converted back to C-60 through deoxygenation with PPh3. Single crystal X-ray structure confirmed the open-cage structure.

  DOI：

  10.1021/jo3026302