zinc(II) bis(2-(dimethylamino)ethyl)amide bis(trimethylsilyl)amide | 1253783-19-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: zinc(II) bis(2-(dimethylamino)ethyl)amide bis(trimethylsilyl)amide
• CAS: 1253783-19-5
• 化学式: C₆H₁₈NSi₂*C₈H₂₀N₃*Zn
• 分子量: 384.044
• InChiKey: ZLWUQTDBZIDCLF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.51
• 重原子数：
  21.0
• 可旋转键数：
  8.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  34.68
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  bis(bis(trimethylsilyl)amido)zinc(II) 、 N'-[2-(二甲基氨基)乙基]-N,N-二甲基乙二胺 以 乙醚 为溶剂， 以71%的产率得到zinc(II) bis(2-(dimethylamino)ethyl)amide bis(trimethylsilyl)amide
  参考文献：
  名称：

  Synthesis and structures of zinc alkoxo, aryloxo and hydroxo complexes with an amidodiamine ligand

  摘要：

  The synthesis and characterization of zinc complexes bearing an amidodiamine ligand, (EtO)(4)Zn(3)[N(CH(2)CH(2)NMe(2))(2)](2) (1), [Et(3)CO)ZnN(CH(2)CH(2)NMe(2))(2)](2) (2) and [(2,6-(i)Pr(2)C(6)H(3)O)ZnN(CH(2)CH(2) NMe(2))(2)](2) (3), [(Me(3)Si)(2)N]Zn[N(CH(2)CH(2)NMe(2))(2)] (4) and [(Me(3)Si)(2)N](2)Zn(2)(OH)[N(CH(2)CH(2)NMe(2))(2)] (5), are reported. Compounds 1-3 are synthesised in the reactions of {Zn[N(CH(2)CH(2)NMe(2))(2)](2)}(2) with 2 equiv. of ethanol, 3-ethyl-3-pentanol and 2,6-diisopropylphenol, respectively. Compound 4 is obtained by the reaction of Zn[N(SiMe(3))(2)](2) with HN(CH(2)CH(2)NMe(2))(2), and compound 5 is synthesised by reacting 4 with 1 equiv. of H(2)O. Compound 4 is characterized by NMR and MS while all of the other compounds are characterized with NMR, MS, elemental analysis and single-crystal X-ray diffraction. Compound 1 is a trinuclear species containing a Zn(3)N(2)O(2) core. Compounds 2 and 3 are dimeric with planar Zn(2)N(2) rings. Compound 5 is dimeric with a planar Zn(2)NO ring. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.06.029