dichlorobis(2-ethylhexyl)germane | 1309886-33-6

• 分子结构分类: 有机化合物 - 有机盐
• 英文名称: dichlorobis(2-ethylhexyl)germane
• CAS: 1309886-33-6
• 化学式: C₁₆H₃₄Cl₂Ge
• 分子量: 369.942
• InChiKey: YDHDOTSQQIONDZ-HOTGVXAUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.34
• 重原子数：
  19.0
• 可旋转键数：
  12.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  dichlorobis(2-ethylhexyl)germane 在 BuLi 、 CuO 、 Pd₂(dba)3 、 P(o-Tol)3 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of Dithienogermole-Containing π-Conjugated Polymers and Applications to Photovoltaic Cells

  摘要：

  Dithienogermole-containing pi-conjugated polymers were prepared by the Stille coupling reactions of distannyldithienogermole and dibromoarenes. The polymers exhibit optical properties similar to those of the previously reported silicon analogues and are usable as the active materials for bulk heterojunction-type organic photovoltaic cells as blends with PC(70)BM.

  DOI：

  10.1021/om200081b
• 作为产物：
  描述：

  溴代异辛烷 、 四氯化锗 在 magnesium 作用下， 以 乙醚 为溶剂， 生成 dichlorobis(2-ethylhexyl)germane
  参考文献：
  名称：

  ジチエノゲルモール化合物

  摘要：

  提供形成自组装螺旋状集合体，并表现出圆偏振发光性的二亚甲基苯酚化合物。通过式（1）表示的二亚甲基苯酚化合物。（R1和R2中的任一或两者具有手性中心；R4为氢或OR3）【图示】图1

  公开号：

  JP2017160162A

文献信息

• Synthesis and Properties of Benzofuran-Fused Silole and Germole Derivatives: Reversible Dimerization and Crystal Structures of Monomers and Dimers
  作者：Fei-Bao Zhang、Yohei Adachi、Yousuke Ooyama、Joji Ohshita

  DOI：10.1021/acs.organomet.6b00222

  日期：2016.7.25

  Benzofuran-fused silole and germole derivatives were synthesized by the reactions of dilithiobi(benzofuran) with R2SiCl2 and R2GeCl2, respectively. Dilithiobi(benzofuran) was prepared by treating diiodobi(benzofuran) with n-BuLi. Optical and electrochemical measurements of the resulting bis(benzofurano)metalloles and their DFT calculations indicated that the introduction of a metallole unit enhanced the conjugation of bi(benzofuran) mainly by raising the HOMO energy level, similarly to the case of bis(benzothieno)silole prepared previously. Interestingly, [2+2] dimers were obtained by recrystallization of the bis(benzofurano)metalloles, and the dimers readily reverted to the respective monomers upon dissolving in solvent. The crystal structures of the dimers and the monomers were determined by X-ray diffraction studies.
• [EN] GERMOLE CONTAINING CONJUGATED MOLECULES AND POLYMERS<br/>[FR] MOLÉCULES CONJUGUÉES ET POLYMÈRES CONTENANT DU GERMOLE
  申请人：UNIV FLORIDA

  公开号：WO2012118728A3

  公开（公告）日：2012-11-22