[4-[4-[6-(2-Methylprop-2-enoyloxy)hexoxy]phenyl]phenyl] 4-methoxybenzoate | 936244-55-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [4-[4-[6-(2-Methylprop-2-enoyloxy)hexoxy]phenyl]phenyl] 4-methoxybenzoate
• 英文别名: [4-[4-[6-(2-methylprop-2-enoyloxy)hexoxy]phenyl]phenyl] 4-methoxybenzoate
• CAS: 936244-55-2
• 化学式: C₃₀H₃₂O₆
• 分子量: 488.58
• InChiKey: BWRBKNKFERRCEQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  36
• 可旋转键数：
  15
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  对甲氧基苯甲酰氯 、 4'-hydroxy-4-phenylphenoxyhexyl methacrylate 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 19.0h， 生成 [4-[4-[6-(2-Methylprop-2-enoyloxy)hexoxy]phenyl]phenyl] 4-methoxybenzoate
  参考文献：
  名称：

  Molecularly Oriented Liquid Crystalline Polymer Films Based on Axis-Selective Photo-Fries Rearrangement

  摘要：

  Four kinds of liquid crystalline polymers (LCPs) with phenyl benzoate side groups were synthesized and their photoinduced reorientation behavior was investigated using linearly polarized (LP) UV light based on the axis-selective photo-Fries rearrangement and thermally induced self-organization of the mesogenic side groups of the materials. Due to different effect of the axis-selectively photoreacted side groups, reorientation direction and its performance depended on the chemical structure of the side groups. Both alignment ability and the molecular rotation of the photoreacted side groups played an important role in the reorientation behavior.

  DOI：

  10.1080/15421406.2013.843257

文献信息

• Molecularly Oriented Liquid Crystalline Polymer Films Based on Axis-Selective Photo-Fries Rearrangement
  作者：Nobuhiro Kawatsuki、Hitomi Matsushita、Naoki Shin、Mami Kurita、Mizuho Kondo

  DOI：10.1080/15421406.2013.843257

  日期：2013.1

  Four kinds of liquid crystalline polymers (LCPs) with phenyl benzoate side groups were synthesized and their photoinduced reorientation behavior was investigated using linearly polarized (LP) UV light based on the axis-selective photo-Fries rearrangement and thermally induced self-organization of the mesogenic side groups of the materials. Due to different effect of the axis-selectively photoreacted side groups, reorientation direction and its performance depended on the chemical structure of the side groups. Both alignment ability and the molecular rotation of the photoreacted side groups played an important role in the reorientation behavior.