(1,1,1,3,3,3-hexamethyldisilaphosphan-2-yl)dimethylaluminum | 869060-62-8

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: (1,1,1,3,3,3-hexamethyldisilaphosphan-2-yl)dimethylaluminum
• CAS: 869060-62-8
• 化学式: C₈H₂₄AlPSi₂
• 分子量: 234.405
• InChiKey: ZWRRYUACZBISNZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.39
• 重原子数：
  12.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  氘代3-氨基-5-吗啉-4-甲基-恶唑-2-啉酮 、 三甲基铝 以 甲苯 为溶剂， 生成 (1,1,1,3,3,3-hexamethyldisilaphosphan-2-yl)dimethylaluminum
  参考文献：
  名称：

  二甲基土金属杂环作为三甲基甲硅烷基化、锗化和甲烷化膦和砷烷的衍生物 - 合成、光谱和结构

  摘要：

  The organo earth-metal heterocycles [Me2MIII-E-((MMe3)-Me-IV)(2)](n) With M-III = Al, Ga, In; E = P, As; M-IV = Si, Ge, Sn and n = 2, 3 (Me = CH3) have been prepared from the dimethyl metal compounds (Me2MX)-X-III (X = Me, H, Cl, OMe, OPh) and the pnicogen derivatives HnE((MMe3)-Me-IV)(3-n) (n = 0, 1) according to known preparation methods. The mass, H-1, C-13, P-31, Si-29, Sn-119 nmr, as well as the ir and Raman spectra have been discussed comparatively; selected representatives are characterized by X-ray structure analyses. The dimeric species with four-membered (E-M-III)(2) rings are isotypic and crystallize in the triclinic space group P (1) over bar, the trimer [Me2In-P(SnMe3)(2)](3) with a strongly puckered (In-P)(3)-ring skeleton crystallizes with two formula units per cell in the same centrosymmetric triclinic space group.

  DOI：

  10.1002/(sici)1521-3749(200005)626:5<1047::aid-zaac1047>3.0.co;2-l