Triethylantimondibromid | 58116-51-1

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Triethylantimondibromid
• 英文别名: Dibromo(triethyl)-lambda5-stibane；dibromo(triethyl)-λ5-stibane
• CAS: 58116-51-1
• 化学式: C₆H₁₅Br₂Sb
• 分子量: 368.743
• InChiKey: DEOYDNHNGJVKMZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.23
• 重原子数：
  9.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Triethylantimondibromid 以 异丙醇 、 苯 为溶剂， 生成 triethylantimony(V) 2-picolinate
  参考文献：
  名称：

  Triorganoantimony(V) carboxylates: Synthesis, characterization and crystal structure of [Me3Sb(O2C–C5H4N)2]·H2O

  摘要：

  Reactions of [R3Sb(OPri)(2)] with N-heterocylic carboxylic acids gave compounds of the type [R3Sb(O2C-Ar)(2)] (1) (R = Me, Et, Pr-i, Ph; Ar = 2-C5H4N, 2-C9H6N). The mono-bromo compound [Me3Sb(Br)(O2C-C5H4N)] (2) exists in equilibrium with [Me3Sb(O2C-C5H4N)(2)] and [Me3SbBr2]. All new compounds have been characterized by IR and NMR (H-1 and C-13{H-1}) spectral data. X-ray structural analysis of one example, [Me3Sb(O2C-C5H4N)(2)], isolated as its monohydrate, revealed an essentially trigonal bipyramidal geometry for the antimony atom defined by three equilaterally disposed methyl groups and two oxygen atoms from monodentate carboxylate groups, in apical positions. The crystal structure is consolidated into a three-dimensional network by cooperative O-H center dot center dot center dot O, O-H center dot center dot center dot N and C-H center dot center dot center dot O interactions. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.07.033
• 作为产物：
  描述：

  Triethyl-stibin-sulfid 生成 Triethylantimondibromid
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sb: Org.Comp.1, 1.1.1.1.1.2, page 18 - 24

  摘要：

  DOI：

文献信息

• Pathways of directed synthesis of iron(II) clathrochelates and polyclathrochelates with non-equivalent capping groups starting from antimony- and germanium-containing precursors
  作者：Yan Z Voloshin、Oleg A Varzatskii、Sergey V Korobko、Mikhail Yu Antipin、Ivan I Vorontsov、Konstantin A Lyssenko、Dmitry I Kochubey、Sergey G Nikitenko、Nataly G Strizhakova

  DOI：10.1016/j.ica.2004.03.050

  日期：2004.8

  surface-immobilized mixed SbSi-capped clathrochelate, which under the action of another capping agent desorbed from the surface gives a mono- or bis-clathrochelate depending on the nature of this agent. An alternative pathway using the bis-capping agents has been implemented for synthesis of bis-clathrochelates when reactive fragments of an initial azomethine ligand demonstrate essentially different chemical properties

  描述了使用半笼螯合物前体和封端基团反应直接合成具有两个非等价封端片段的笼形螯合物和聚笼形螯合物的替代方法。锑封盖的铁（II）笼形螯合物在重金属化（封端基团交换）反应中的不稳定性允许获得通式为FeNx 3 X 1 X 2和（FeNx 3 X 1）2 X 2的单-和双-笼形螯合物（其中Nx 2-是环己二酮-1,2-二肟二阴离子； X 1，X 2是不同的封端基团）。第一个独特的二氧肟酸盐[Fe（HNx）3（Sb（C6 H 5）3）]（ClO 4）分离并表征了半笼螯合物。该络合物与不同的单官能和双官能交联剂（路易斯酸）的反应导致形成具有非等价封端基团的笼形螯合物分子。具有不稳定的三乙基锑封端基团的笼形螯合物在二氧化硅作为催化剂的存在下进行了重金属化。第一阶段导致表面固定化的混合SbSi封端的笼形螯合物的形成，在另一种从表面解吸的封端剂的作用下，取决于该试剂的性质，该混合物可生成单笼形或双笼形螯合物
• New antimony-capped iron(II) and cobalt(III) clathrochelate precursors of the polytopic hybrid cage complexes: Synthesis, X-ray structures and electrochemistry
  作者：Yan Z. Voloshin、Oleg A. Varzatskii、Alexander S. Belov、Zoya A. Starikova、Alexander V. Dolganov、Tatiana V. Magdesieva

  DOI：10.1016/j.poly.2007.09.008

  日期：2008.1

  Direct template macrocyclization of the three dimethylglyoxime molecules on the iron(II) ion and the capping of nonmacrocyclic K3CoDm3 tris-dimethylglyoximate with triethylantimony(V) derivatives led to the formation of triethylantimony-capped iron(II) and cobalt(III) clathrochelates. The complexes obtained have been characterized using elemental analysis, MALDI-TOF mass, IR, UV–Vis, 57Fe Mössbauer

  铁（II）离子上的三个二甲基乙二肟分子的直接模板大环化以及用三乙基锑（V）衍生物封端非大环K 3 CoDm 3三甲基二甲基乙二肟酸酯导致三乙基锑封端的铁（II）和钴（III）的形成笼形螯合物。使用元素分析，MALDI-TOF质量，IR，UV-Vis，57 FeMössbauer以及1 H和13 C NMR光谱学和X射线晶体学对所得复合物进行了表征。讨论了包封的金属离子，封端基团和螯合物碎片的性质对笼形螯合物骨架几何形状的影响。循环伏安图显示可分配给Fe 2 + / 3 +的氧化和还原波以及包封的金属离子的Co 2 + / 3 +对。
• Clathrochelate iron(II) tris-nioximates with non-equivalent capping groups and their precursors: synthetic strategies, X-ray structure, and reactivity
  作者：Genrikh E. Zelinskii、Alexander S. Belov、Alexander S. Chuprin、Alexander A. Pavlov、Anna V. Vologzhanina、Ekaterina G. Lebed、Margarita G. Bugaenko、Yan Z. Voloshin

  DOI：10.1080/00958972.2017.1348602

  日期：2017.7.3

  product, isolated in a high yield; it was X-ray structurally characterized. The geometry of FeN6-coordination polyhedra of the above semi- and clathrochelates is intermediate between a trigonal prism and a trigonal antiprism; that of the monocapped iron(II) semiclathrochelate is more TAP-distorted and its pseudoencapsulated iron(II) ion is shifted from the center of this polyhedron by 0.02 Å in the

  摘要 使用等摩尔量的硼酸和 4-乙烯基苯基硼酸以铁 (II) 离子为基质进行镍肟模板交联，得到单和二乙烯基封端的笼形螯合物产物的混合物，其以中等产率进行色谱分离并表征为X射线衍射。使用其二甲氧基硼封端的笼形螯合物前体的金属转移（再硼化），也以低产率获得了具有非等价封端基团的目标复合物 FeNx3(BOCH3)(4-BC6H4CH=CH2)。用作为双功能路易斯酸剂的苯-1,4-二硼酸对单甲氧基硼封端的笼络合物进行再硼化，主要提供了具有末端 B(OH)2 基团的 1:1 再硼化的笼形螯合物产物。具有不稳定的三乙基锑封端基团的铁 (II) 笼形螯合物在硅胶表面发生金属转移，得到固定的 Sb、Si 封端的大双环中间体。其用 4-乙烯基苯基硼酸解吸出人意料地得到单乙烯基封端的半笼螯合铁（II）作为主要产物，以高产率分离；它是 X 射线结构表征。上述半和笼形螯合物的 FeN6 配位多面体的几何形状介于三棱柱和三棱反棱柱之间；单封端的铁
• Peroxides of elements other than carbon. Part XVII. The reaction of trialkylstibines and trialkylbismuthines with t-butyl hydroperoxide and with oxygen
  作者：Alwyn G. Davies、Simon C. W. Hook

  DOI：10.1039/j39710001660

  日期：——

  t-Butyl hydroperoxide reacts with trialkylstibines, R3M, to give the corresponding stibine oxides, R3MO, but with trialkylbismuthines to give products such as RO·OBut, ROH, and ROR. Both reactions are thought to involve the intermediate metallonium ion R3MOH, which undergoes nucleophilic attack on H when M = Sb, and on R when M = Bi.

  叔丁基氢过氧化物与三烷基stibines R 3 M反应，生成相应的氧化锑，R 3 MO，但与三烷基双变色氨酸生成RO·OBu t，ROH和ROR等产物。认为这两个反应都涉及中间体金属离子R 3 MOH，当M = Sb时，它对H发生亲核攻击，而当M = Bi时，对R发生亲核攻击。
• Synthesis, X-ray structure and electrochemical properties of hybrid binuclear metallophthalocyaninate-capped tris-pyridineoximates
  作者：Semyon V. Dudkin、Alexander S. Belov、Yulia V. Nelyubina、Anastasia V. Savchuk、Alexander A. Pavlov、Valentin V. Novikov、Yan Z. Voloshin

  DOI：10.1039/c7nj00131b

  日期：——

  hafnium(IV) phthalocyaninates (Pc) to give binuclear MPc-capped tris-pyridineoximates. The obtained hybrid complexes and their precursors were thoroughly characterized (among others, by single-crystal X-ray diffraction), and their redox properties were studied by cyclic and differential pulse voltammetry.

  通过将2-乙酰基吡啶肟与三乙基锑（V）二溴化物在相应的金属离子上进行模板缩合反应，制得了具有不稳定的三乙基锑交联基团的新的带有锑的封端的铁和镍（II）三吡啶氧肟酸酯。它们容易与路易斯酸性锆和ha（IV）酞菁（Pc）进行金属转移反应（封端基团交换），得到双核MPc封端的三吡啶氧肟酸酯。对得到的杂化配合物及其前体进行了全面表征（除其他外，通过单晶X射线衍射），并通过循环和差分脉冲伏安法研究了它们的氧化还原性能。