zinc-struvite | 136783-44-3

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物
• 英文名称: zinc-struvite
• 英文别名: ZINC ammonium phosphate hexahydrate；azanium;zinc;phosphate;hexahydrate
• CAS: 136783-44-3
• 化学式: H₄N*H₁₂O₆Zn*O₄P
• 分子量: 286.492
• InChiKey: PXMMNHNPTDDALK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -7.4
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  93.2
• 氢给体数：
  7
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  ammonium dihydrogen phosphate 、 zinc(II) sulfate 在 ammonium hydroxide 作用下， 以 水 为溶剂， 生成 zinc-struvite
  参考文献：
  名称：

  Electron paramagnetic resonance study of doped synthetic crystals of struvite and its zinc analogue

  摘要：

  The electron paramagnetic resonance (EPR) technique has been used to study the Mn2+ paramagnetic impurity complexes in synthetic struvite (MgNH4PO4.6H2O) and the zinc isomorph (ZnNH4PO4.6H2O). EPR of VO2+ ion complexes in vanadyl doped crystals of the zinc isomorph of struvite has also been studied. Two differently oriented, but otherwise identical complexes of both Mn2+ ion and VO2+ ion are found in these crystals. The spin Hamiltonian parameters indicate a large orthorhombic distortion of the [Mn2+(H2O)6] octahedra and an axial symmetry of the vanadyl complexes. The results indicate that in both manganese and vanadyl complexes, the metal ions have covalent bonding with the ligands.

  DOI：

  10.1016/0584-8539(91)80149-d