2-[bis(2-trimethylsilylazanidylethyl)amino]ethyl-trimethylsilylazanide;molecular nitrogen;molybdenum(3+) | 187409-98-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 2-[bis(2-trimethylsilylazanidylethyl)amino]ethyl-trimethylsilylazanide;molecular nitrogen;molybdenum(3+)
• CAS: 187409-98-9
• 化学式: C₁₅H₃₉MoN₆Si₃
• 分子量: 483.711
• InChiKey: AHSLLIXHMMRLRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.94
• 重原子数：
  25.0
• 可旋转键数：
  12.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  93.12
• 氢给体数：
  0.0
• 氢受体数：
  3.0

文献信息

• O'Donoghue, Myra B.; Davis, William M.; Schrock, Richard R., Inorganic Chemistry, 1998, vol. 37, # 20, p. 5149 - 5158
  作者：O'Donoghue, Myra B.、Davis, William M.、Schrock, Richard R.

  DOI：——

  日期：——
• O'Donoghue, Myra B.; Davis, William M.; Schrock, Richard R., Inorganic Chemistry, 1999, vol. 38, # 2, p. 243 - 252
  作者：O'Donoghue, Myra B.、Davis, William M.、Schrock, Richard R.、Reiff, William M.

  DOI：——

  日期：——
• Synthesis of [(Me₃SiNCH₂CH₂)₃N]³^- and [(C₆F₅NCH₂CH₂)₃N]³^- Complexes of Molybdenum and Tungsten That Contain CO, Isocyanides, or Ethylene
  作者：George E. Greco、Myra B. O'Donoghue、Scott W. Seidel、William M. Davis、Richard R. Schrock

  DOI：10.1021/om990748u

  日期：2000.3.1

  Paramagnetic complexes of the type [N3N]MoL ([N3N](3-) = [(Me3SiNCH2CH2)(3)N](3-); L = CO, RNC, C2H4) have been prepared by displacing dinitrogen from [N3N]Mo(N-2). [N3N]Mo(CO) was reduced by magnesium powder in the presence of Me3SiCl to yield the diamagnetic oxycarbyne complex [N3N]Mo=COSiMe3, while oxidation of [N3N]Mo(CN-t-Bu) with [Cp2Fe]OTf yielded [N3N]Mo(CN-t-Bu)}OTf. Thermolysis of [N3N]Mo(CN-t-Bu) resulted in loss of a t-Bu radical to yield [N3N]Mo(CN), which was structurally characterized, [N3NFML ([N3NF](3-) = [(C6F5NCH2CH2)(3)N](3-) M = Mo, W; L = CO, RNC) complexes have been prepared by one-electron reduction of [N3NF]M(OTf) in the presence of L. An X-ray study of [N3NF]W(CN-t-Bu) showed it to contain a bend isocyanide ligand. Anionic CO complexes were prepared by the two-electron reduction of [N3NF]M(OTf) in the presence of CO. An X-ray study of [N3NF]W(CO)(2)}Na(ether)(3) revealed it to have a pseudo-octahedral structure in which sodium is bound to the CO trans tb the amine donor atom. Treatment of [N3NF]M(CO)}(-) complexes with Me3SiCl gave oxycarbyne complexes [N3NF]M=COSiMe3. Reaction of [N3NF]WCO with V(Mes)(3)(THF) yielded [N3NF]W(CO)V(Mes)(3), the structure of which was determined in an X-ray study. Cationic [N3NF](3-) complexes could be prepared that contain up to 3 equiv of isocyanide. An X-ray study of [N3NF]W(CN-t-Bu)(3)}BPh4 showed it to be a seven-coordinate species with one isocyanide located in the equatorial plane and the other two isocyanide ligands in the apical pocket. Reduction of [N3NF]W(OTf) under ethylene gave [N3NF]W(C2H4), which could be oxidized to yield diamagnetic [N3NF]W(C2H4)}OTf.
• “Fixation” of Dinitrogen by Molybdenum and the Formation of a Trigonal Planar Iron−Tris[molybdenum(dinitrogen)] Complex
  作者：Myra B. O'Donoghue、Nadia C. Zanetti、William M. Davis、Richard R. Schrock

  DOI：10.1021/ja963822y

  日期：1997.3.1