(diethylenetriamine)MoO3 | 19478-36-5

• 分子结构分类: 有机化合物 - 有机盐
• 英文名称: (diethylenetriamine)MoO3
• CAS: 19478-36-5；23300-44-9
• 化学式: C₄H₁₃MoN₃O₃
• 分子量: 247.106
• InChiKey: QDTHYSVAMBUAFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (diethylenetriamine)MoO3 以 盐酸 为溶剂， 以74%的产率得到bis(3-aza-1,5-pentamethylenediammonium) octamolybdate(VI) hexahydrate
  参考文献：
  名称：

  Reactions of MoO3 with diethylenetriamine (dien): Syntheses, solid-state characterization and thermal behaviour. Molecular and crystal structure of a second polymorph of (H3dien)2[Mo7O24]·4H2O

  摘要：

  The reaction Of MoO3 with diethylenetriamine in aqueous solution yields four compounds: two polymorphs of bis(diethylenetriammonium) heptamolybdate(VI) tetrahydrate, (H3dien)2[Mo7O24].4H2O (1 and 2), bis(3-aza-1,5-pentamethylenediaminonium) octamolybdate(VI) hexahydrate, (H2dien)2[Mo8O26].6H2O (3), and the oxocomplex diethylenetriaminetrioxomolybdenum(VI), [MoO3(dien)] (4). The compounds were characterized by means of thermal analyses and IR spectroscopy. The crystal structure of 1 was determined by X-ray diffraction. Compounds 1 and 2 are an unprecedented case ot' polymorphism in discrete polyoxomolybdates and their syntheses experimentally confirm the ability of polyoxometallates to promote the stacking of a large number Of organic molecules by means of an extended network of hydrogen contacts. Both structures contain discrete[Mo7O24]6- polyanions, diethylenetriammonium cations and water molecules connected through hydrogen bonding interactions which are responsible for a different crystal packing in both compounds. In 1 the Mo(5)-O(17) bond length, 2.675(4) angstrom, is significantly longer than those observed for other organoammonium heptamolybdates that exhibit photochemical properties and antitumour activity. This long molybdenum oxygen distance may play an important role in the possible photochromism and anticancer activity of this compound.

  DOI：

  10.1016/s0277-5387(00)83158-7
• 作为产物：
  描述：

  molybdenum(VI) oxide 、 bis(diethylenetriammonium) heptamolybdate(VI) tetrahydrate 以 水 为溶剂， 以56%的产率得到(diethylenetriamine)MoO3
  参考文献：
  名称：

  Reactions of MoO3 with diethylenetriamine (dien): Syntheses, solid-state characterization and thermal behaviour. Molecular and crystal structure of a second polymorph of (H3dien)2[Mo7O24]·4H2O

  摘要：

  The reaction Of MoO3 with diethylenetriamine in aqueous solution yields four compounds: two polymorphs of bis(diethylenetriammonium) heptamolybdate(VI) tetrahydrate, (H3dien)2[Mo7O24].4H2O (1 and 2), bis(3-aza-1,5-pentamethylenediaminonium) octamolybdate(VI) hexahydrate, (H2dien)2[Mo8O26].6H2O (3), and the oxocomplex diethylenetriaminetrioxomolybdenum(VI), [MoO3(dien)] (4). The compounds were characterized by means of thermal analyses and IR spectroscopy. The crystal structure of 1 was determined by X-ray diffraction. Compounds 1 and 2 are an unprecedented case ot' polymorphism in discrete polyoxomolybdates and their syntheses experimentally confirm the ability of polyoxometallates to promote the stacking of a large number Of organic molecules by means of an extended network of hydrogen contacts. Both structures contain discrete[Mo7O24]6- polyanions, diethylenetriammonium cations and water molecules connected through hydrogen bonding interactions which are responsible for a different crystal packing in both compounds. In 1 the Mo(5)-O(17) bond length, 2.675(4) angstrom, is significantly longer than those observed for other organoammonium heptamolybdates that exhibit photochemical properties and antitumour activity. This long molybdenum oxygen distance may play an important role in the possible photochromism and anticancer activity of this compound.

  DOI：

  10.1016/s0277-5387(00)83158-7

文献信息

• Formation of oxometal complexes by the oxidative decarbonylation of metal carbonyls
  作者：J.M. Wallis、J.K. Kochi

  DOI：10.1016/s0020-1693(00)80589-7

  日期：1989.6
• Roman, Pascual; Luque, Antonio; Gutierrez-Zorrilla, Juan M., Acta Crystallographica, Section C: Crystal Structure Communications, 1991, vol. 47, p. 188 - 190
  作者：Roman, Pascual、Luque, Antonio、Gutierrez-Zorrilla, Juan M.

  DOI：——

  日期：——