Novel Organically Templated Vanadyl(IV) Diarsenate and Monoarsenate with Chain Structures: Solvothermal Synthesis and Characterization of (H3NC2H4NH3)[VO(H2O)As2O7] and (H3NC2H4NH3)0.5[VO(H2O)AsO4]
摘要:
The synthesis and characterization of two 1D chain vanadyl(IV) arsenates are described; one infinite chain is built up of VO5(H2O) octahedra and As2O7 bitetrahedra, and the other is formed of edge-sharing [V2O8-(H2O)(2)] bioctahedra and AsO4 tetrahedra.