| 104855-66-5

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 104855-66-5
• 化学式: C₅H₁₀HgOS₂
• 分子量: 350.856
• InChiKey: RNYPVGABXHIKFW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium isopropylxanthate 、 氯化甲基汞 以 二氯甲烷 为溶剂， 以73%的产率得到
  参考文献：
  名称：

  Supramolecular self-assembly in the crystal structures of methylmercury xanthates, MeHgS(S)COR, R=Et, iPr and CH2Ph

  摘要：

  Methylmercury(II) xanthates, MeHgS(S)COR, with R = Et, Pr-i and CH2Ph, form unidimensional, supramolecular self-assembled, tape-like arrays in the solid state, based upon Hg...S intermolecular secondary interactions. In the compounds with R = Et and Pr-i the individual molecules form double chains (tapes) weakly interacting with neighbouring arrays, while the compound with R = CH2Ph forms dimeric units, which are further associated into infinite tapes, not interacting with each other. Primary Hg-S bonds are in the range 2.378(5)-2.391(3) Angstrom, intramolecular Hg...S secondary bonds leading to chelation are in the range 3.179(5)-3.259(3) Angstrom, whereas intermolecular Hg...S secondary interactions cover a broader range, from 3.403(4) to 4.22(1) Angstrom. (C) 2001 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0020-1693(01)00820-9