sodium 4-((4-(methylamino)phenyl)diazenyl)benzenesulfonate | 1050509-91-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: sodium 4-((4-(methylamino)phenyl)diazenyl)benzenesulfonate
• 英文别名: methyl orange
• CAS: 1050509-91-5
• 化学式: C₁₃H₁₂N₃O₃S*Na
• 分子量: 313.312
• InChiKey: IPSXUDSUKVUSGC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.05
• 重原子数：
  21.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  93.95
• 氢给体数：
  1.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  methyl orange 在 Pt-HCa₂Nb₃O₁₀ 作用下， 以 水 为溶剂， 反应 2.0h， 生成 sodium 4-((4-(methylamino)phenyl)diazenyl)benzenesulfonate 、 、 4-aminoazobenzene-4'-sulfonic acid sodium
  参考文献：
  名称：

  Room temperature oxidation of methyl orange and methanol over Pt–HCa₂Nb₃O₁₀and Pt–WO₃catalysts without light

  摘要：

  层状半导体 PtâHCa2Nb3O10 可催化甲基橙的室温空气氧化反应。在催化甲醇与空气的反应方面，它也比 PtâWO3 更有效。PtâHCa2Nb3O10 可以作为一种温和的氧化催化剂得到广泛应用。

  DOI：

  10.1039/c0cc03553j

文献信息

• Recycled carbon (RC) materials made functional: An efficient heterogeneous Mn-RC catalyst
  作者：E. Seristatidou、A. Mavrogiorgou、I. Konstantinou、M. Louloudi、Y. Deligiannakis

  DOI：10.1016/j.molcata.2015.04.001

  日期：2015.7

  A Mn-II-Schiff-base catalyst was synthesized and covalently immobilized onto Pyrolytic Carbon surface from waste tyres (PCox), resulting in the heterogeneous catalyst Mn-II-L@PCox which was evaluated for degradation of methyl orange (MO) using NaIO4 as oxidant. Importantly, no additive as co-catalyst was needed. For comparison, a reference heterogeneous catalyst Mn-II-L@AC(ox) was also tested, using Activated Carbon (AC(ox)) as carbon matrix. The catalytic and recyclability data of Mn-II-L@PCox catalyst demonstrate that it is superior, in terms of TONs and TOFs vs. Mn-II-L@AC(ox). To study the reaction path, electron paramagnetic resonance spectroscopy was used to monitor the redox evolution of the Mn-centers. Furthermore, a full mapping of the catalytic degradation of MO and product formation was carried out using LC-MS and HPLC. Combining catalytic and spectroscopic data we discuss the protective effect of the PCox matrix on Mn-centers: it allows their rapid redox evolution to higher oxidation states. (C) 2015 Elsevier B.V. All rights reserved.