molecular chlorine;phosphane | 180728-10-3

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物
• 英文名称: molecular chlorine;phosphane
• CAS: 180728-10-3
• 化学式: Cl₂*H₃P
• 分子量: 104.904
• InChiKey: OUNLASCJUPMYQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.44
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  氯 、 phosphan 以 gaseous matrix 为溶剂， 生成 molecular chlorine;phosphane
  参考文献：
  名称：

  Isolation of stable intermediates in reactive gas mixtures: Rotational spectrum of H₃P...Cl₂in a pulsed jet

  摘要：

  The weakly bound dimer H3P...Cl2 has been isolated in a pulsed jet by keeping the highly reactive components H3P and Cl2 separate until the point at which they expand into the evacuated Fabry–Pérot cavity of a pulsed-nozzle Fourier-transform microwave spectrometer. The rotational spectra of the three symmetric-top isotopomers H3P...35Cl 35Cl, H3P...35Cl 37Cl, and H3P...37Cl 35Cl detected in this way have been analyzed to give the ground-state spectroscopic constants B0, DJ, DJK, χ1(Cl), and χ2(Cl). Comparison of the dimer properties determined from the spectroscopic constants of H3P...Cl2 with those of the hydrogen-bonded dimer H3P...HCl indicates that charge transfer is not predominant in the interaction of PH3 and Cl2. Some parallels in the properties of B...Cl2 and B...HCl are discussed for B=PH3 and HF.

  DOI：

  10.1063/1.464011