3-benzamidophenyl benzoate | 7504-88-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 3-benzamidophenyl benzoate
• 英文别名: 1-benzoylamino-3-benzoyloxy-benzene；1-Benzoylamino-3-benzoyloxy-benzol；O.N-Dibenzoyl-(3-amino-phenol)；(3-Benzamino-phenyl)-benzoat；benzoic acid 3-benzoylamino-phenyl ester；N,O-Dibenzoyl-3-amino-phenol；(3-Benzamidophenyl) benzoate
• CAS: 7504-88-3
• 化学式: C₂₀H₁₅NO₃
• 分子量: 317.344
• InChiKey: XOEOCDRIMVRQCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  55.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-benzamidophenyl benzoate 在 硝酸 作用下， 生成 1-benzoylamino-5-benzoyloxy-2,4-dinitro-benzene
  参考文献：
  名称：

  Reverdin; Widmer, Chemische Berichte, 1913, vol. 46, p. 4074

  摘要：

  DOI：
• 作为产物：
  描述：

  间苯二酚 在 sodium hydroxide 、 ammonium chloride 、 氨 作用下， 生成 3-benzamidophenyl benzoate
  参考文献：
  名称：

  Ikuta, American Chemical Journal, 1893, vol. 15, p. 40

  摘要：

  DOI：

文献信息

• ‘Green’ methodology for efficient and selective benzoylation of nucleosides using benzoyl cyanide in an ionic liquid
  作者：Ashok K. Prasad、Vineet Kumar、Shashwat Malhotra、Vasulinga T. Ravikumar、Yogesh S. Sanghvi、Virinder S. Parmar

  DOI：10.1016/j.bmc.2005.04.038

  日期：2005.7

  Benzoyl cyanide in the ionic liquid 1-methoxyethyl-3-methylimidazolium methanesulfonate has been employed as a 'green' alternative and mild reaction condition protocol to conventional pyridine-benzoyl chloride system for efficient and selective benzoylation of nucleosides (of both the ribo- and deoxyribo-series) at ambient temperatures. The use of benzoyl cyanide-ionic liquid combination has been successfully

  离子液体1-甲氧基乙基-3-甲基咪唑鎓甲磺酸盐中的苯甲酰氰已被用作常规吡啶-苯甲酰氯系统的“绿色”替代方案，反应条件温和，可用于核糖（核糖和脱氧核糖两者）的有效和选择性苯甲酰化系列）。苯甲酰基氰化物-离子液体组合的使用已成功扩展到酚，芳族胺，苄醇，脂肪族二醇，3-氨基苯酚和2-氨基苄基醇的高效苯甲酰化，这表明该苯甲酰化体系的多功能性。
• 4-amino-thieno[3,2-c] pyridine-7-carboxylic acid derivatives
  申请人：Bartkovitz Joseph David

  公开号：US20070060607A1

  公开（公告）日：2007-03-15

  The present invention relates to compounds of the formula medicaments containing them and the use of these compounds as pharmaceutically active agents. The compounds exhibit activity as Raf kinase inhibitors and therefore may be useful for the treatment of diseases mediated by said kinases, especially as anticancer agents.

  本发明涉及公式化合物、含有它们的药物以及将这些化合物用作药用活性剂的用途。这些化合物表现出作为Raf激酶抑制剂的活性，因此可能对通过该激酶介导的疾病的治疗有用，特别是作为抗癌剂。
• Solid catalyst component for use in olefin polymerisation, catalyst, and application thereof
  申请人：BEIJING LIHE TECHNOLOGY LTD

  公开号：US11136421B2

  公开（公告）日：2021-10-05

  Provided in the present invention is a solid catalyst component for use in olefin polymerisation, comprising Mg, Ti, a halogen, and at least one electron donor, the electron donor being a 2-substituted amino-phenyl ester compound selected from general formula (I). Also disclosed in the present invention are a catalyst comprising the solid catalyst component, and an application for the catalyst in olefin polymerisation, particularly in propylene polymerization. Also provided in the present invention is a high activity catalyst, said catalyst being able to obtain polypropylene of high isotacticity and wide molecular weight distribution, and not requiring an external electron donor to obtain high isotacticity polypropylene; during polymerization, Al/Ti and Al/Si are reduced, the polymerization time is lengthened, and high activity can still be maintained, suitable for producing low-ash polymers.

  本发明提供了一种用于烯烃聚合的固体催化剂组分，包括 Mg、Ti、卤素和至少一种电子供体，电子供体为选自通式 (I) 的 2-取代氨基苯基酯化合物。本发明还公开了一种包含固体催化剂组分的催化剂，以及该催化剂在烯烃聚合，特别是丙烯聚合中的应用。本发明还提供了一种高活性催化剂，所述催化剂能够获得高同素异形度和宽分子量分布的聚丙烯，并且不需要外部电子供体即可获得高同素异形度聚丙烯；在聚合过程中，Al/Ti 和 Al/Si 降低，聚合时间延长，仍可保持高活性，适用于生产低灰分聚合物。
• Gal; Krasznai, Acta Chimica Academiae Scientiarum Hungaricae, 1958, vol. 17, p. 171,176
  作者：Gal、Krasznai

  DOI：——

  日期：——
• SOLID CATALYST COMPONENT FOR USE IN OLEFIN POLYMERISATION, CATALYST, AND APPLICATION THEREOF
  申请人：BEIJING LIHE TECHNOLOGY LTD

  公开号：US20200071430A1

  公开（公告）日：2020-03-05

  Provided in the present invention is a solid catalyst component for use in olefin polymerisation, comprising Mg, Ti, a halogen, and at least one electron donor, the electron donor being a 2-substituted amino-phenyl ester compound selected from general formula (I). Also disclosed in the present invention are a catalyst comprising the solid catalyst component, and an application for the catalyst in olefin polymerisation, particularly in propylene polymerization. Also provided in the present invention is a high activity catalyst, said catalyst being able to obtain polypropylene of high isotacticity and wide molecular weight distribution, and not requiring an external electron donor to obtain high isotacticity polypropylene; during polymerization, Al/Ti and Al/Si are reduced, the polymerization time is lengthened, and high activity can still be maintained, suitable for producing low-ash polymers.