aluminum bromide, dimer | 18898-34-5

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属盐
• 英文名称: aluminum bromide, dimer
• 英文别名: Dialuminum;hexabromide；dialuminum;hexabromide
• CAS: 18898-34-5
• 化学式: Al₂Br₆
• 分子量: 533.387
• InChiKey: XMJCPTNSVZSWHK-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  4.31
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  aluminum bromide, dimer 、 乙硫醚 生成
  参考文献：
  名称：

  Grigor'ev, A. A.; Kondrat'ev, Yu. V.; Suvorov, A. V., Journal of general chemistry of the USSR, 1982, vol. 52, p. 1726 - 1730

  摘要：

  DOI：

文献信息

• ——
  作者：V. B. Murachev、A. I. Nesmelov

  DOI：10.1023/a:1009525201771

  日期：——

  The reaction of aluminum bromide with benzene in n-hexane was studied by Al-27 NMR spectroscopy in the temperature range from -80 to +20 degreesC. The formation Of C6H6. Al2Br6 (1:2) complexes is accompanied by broadening of the resonance line with delta 178. No peak splitting following a decrease in the temperature was observed but the temperature dependence of the line width passed through a maximum near -60 degreesC, A procedure for determination of the constant K for the formation of 1:2 complexes at -20, 0, and +20 degreesC based on the line broadening with an increase in the C6H6 : Al2Br6 molar ratio was proposed. The thermodynamic parameters of complex formation, DeltaG, DeltaH, and DeltaS, were calculated.
• Laumanns, Reinhard; Schaefer, Harald, Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Laumanns, Reinhard、Schaefer, Harald

  DOI：——

  日期：——