dimethylindium | 129064-95-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: dimethylindium
• CAS: 129064-95-5
• 化学式: C₂H₆In
• 分子量: 144.89
• InChiKey: SZEJQLSRYARYHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.79
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  三甲基铟 以 gas 为溶剂， 生成 indium 、 monomethylindium 、 dimethylindium
  参考文献：
  名称：

  Photolysis of group III (Al, Ga, In) trimethyl compounds: Detection of organic photofragments CH3 and C2H6 by picosecond laser mass spectroscopy

  摘要：

  The metal alkyls trimethylaluminum (TMA), trimethylgallium (TMG) and trimethylindium (TMI) were decomposed under collision-free conditions by tunable UV laser light in the range 190-310 nm and the photoproducts detected by laser mass spectroscopy using short and ultrashort laser pulses. At moderate laser fluences, these compounds decompose via a one-photon process. The simple separation of one or two methyl ligands leads to the metal-dimethyl radical (Al(CH3)2, Ga(CH3)2, In(CH3)2), and the metal-monomethyl radical (AlCH3, GaCH3, InCH3) as photoproducts. The vibronically excited metal-dimethyl radical can further decay - without the absorption of additional photons - into the metal atom plus ethane molecule. This has been proved for the first time by laser mass-spectroscopic detection of the ethane molecule as being a direct photoproduct of the investigated trialkyls. The quantum yields for the wavelength-dependent fragmentation are presented.

  DOI：

  10.1016/0009-2614(91)87056-h

文献信息

• Photodissociation of adsorbed trimethylindium
  作者：J. S. Horwitz、E. Villa、D. S. Y. Hsu

  DOI：10.1021/j100381a048

  日期：1990.9
• Photolysis of group III (Al, Ga, In) trimethyl compounds: Detection of organic photofragments CH3 and C2H6 by picosecond laser mass spectroscopy
  作者：Th. Beuermann、M. Stuke

  DOI：10.1016/0009-2614(91)87056-h

  日期：1991.3

  The metal alkyls trimethylaluminum (TMA), trimethylgallium (TMG) and trimethylindium (TMI) were decomposed under collision-free conditions by tunable UV laser light in the range 190-310 nm and the photoproducts detected by laser mass spectroscopy using short and ultrashort laser pulses. At moderate laser fluences, these compounds decompose via a one-photon process. The simple separation of one or two methyl ligands leads to the metal-dimethyl radical (Al(CH3)2, Ga(CH3)2, In(CH3)2), and the metal-monomethyl radical (AlCH3, GaCH3, InCH3) as photoproducts. The vibronically excited metal-dimethyl radical can further decay - without the absorption of additional photons - into the metal atom plus ethane molecule. This has been proved for the first time by laser mass-spectroscopic detection of the ethane molecule as being a direct photoproduct of the investigated trialkyls. The quantum yields for the wavelength-dependent fragmentation are presented.