2-Propanol, 1,3-bis(4-(1-(4-(1-methyl-1-(4-(2-oxiranylmethoxy)phenyl)ethyl)phenyl)-1-(4-(2-oxiranylmethoxy)phenyl)ethyl)phenoxy)- | 180063-56-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 2-Propanol, 1,3-bis(4-(1-(4-(1-methyl-1-(4-(2-oxiranylmethoxy)phenyl)ethyl)phenyl)-1-(4-(2-oxiranylmethoxy)phenyl)ethyl)phenoxy)-
• 英文别名: 1,3-bis[4-[1-[4-(oxiran-2-ylmethoxy)phenyl]-1-[4-[2-[4-(oxiran-2-ylmethoxy)phenyl]propan-2-yl]phenyl]ethyl]phenoxy]propan-2-ol
• CAS: 180063-56-3
• 化学式: C₇₃H₇₆O₁₁
• 分子量: 1129.4
• InChiKey: UADFTMJGFBALAH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15
• 重原子数：
  84
• 可旋转键数：
  28
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.34
• 拓扑面积：
  126
• 氢给体数：
  1
• 氢受体数：
  11

文献信息

• AROMATIC AMINE COMPOUND, CURING AGENT FOR EPOXY COMPOUND, CURABLE COMPOSITION, CURED PRODUCT, METHOD FOR PRODUCING CURED PRODUCT, AND METHOD FOR PRODUCING AROMATIC AMINE COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20210130284A1

  公开（公告）日：2021-05-06

  An aromatic amine compound capable of satisfactorily forming a cured product having exceptional alkali resistance by reaction with an epoxy compound; a curing agent for an epoxy compound, the curing agent including the aromatic amine compound; a curable composition including the curing agent for an epoxy compound; a cured product of the curable composition; a method for producing the cured product; and a method for producing the abovementioned aromatic amine compound. The aromatic amine compound has a structure such that a specific position in a central skeleton comprising a fused ring such as a fluorene ring is substituted with a side-chain group including two aromatic groups linked by a flexible bond such as an amide bond, at least one amino group is bonded to the end of the side-chain group, and the structure has no hydroxyl groups.

  一种芳香胺化合物，通过与环氧化合物反应能够满意地形成具有异常碱性抗性的固化产品；一种环氧化合物的固化剂，该固化剂包括芳香胺化合物；一种包括环氧化合物的固化剂的可固化组合物；可固化组合物的固化产品；生产所述固化产品的方法；以及生产上述芳香胺化合物的方法。该芳香胺化合物具有这样的结构，即中心骨架中的特定位置包括类似于芴环的融合环，该位置被取代为包括通过柔性键（如酰胺键）连接的两个芳香基的侧链基团，至少一个氨基固定在侧链基团的末端，并且该结构不含羟基。
• CURABLE COMPOSITION, CURED PRODUCT, AND COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20220177641A1

  公开（公告）日：2022-06-09

  a curable composition that gives a cured product exhibiting a high refractive index and a surface without defects such as roughness or cracks, a cured product of the composition, and a compound that may be blended to the composition. In a curable composition including a triazine compound having three aromatic-ring-containing groups each bonded to the triazine ring via an amino group, an aromatic-ring-containing group having a specific structure having a radically polymerizable group-containing group or a cationically polymerizable group-containing group is used as at least one of the three aromatic-ring-containing groups bonded to the triazine ring in the triazine compound mentioned above.

  一种可治愈的组合物，可产生具有高折射率和表面无缺陷（如粗糙或裂纹）的固化产品，该组合物的固化产品以及可混合到该组合物中的化合物。在包括三嗪化合物的可固化组合物中，每个含有芳香环的基团均通过氨基与三嗪环结合，具有特定结构的含芳香环基团具有具有自由基聚合基团或阴离子聚合基团的群组，至少用作上述三嗪化合物中与三嗪环结合的三个芳香环含基团之一。
• PROCESS FOR PREPARATION OF ALICYCLIC DIEPOXY COMPOUNDS, CURABLE EPOXY RESIN COMPOSITIONS, EPOXY RESIN COMPOSITIONS FOR THE ENCAPSULATION OF ELECTRONIC COMPONENTS, STABILIZERS FOR ELECTRICAL INSULATING OILS, AND CASTING EPOXY RESIN COMPOSITIONS FOR ELECTRICAL INSULATION
  申请人：DAICEL CHEMICAL INDUSTRIES, Ltd.

  公开号：EP1541567A1

  公开（公告）日：2005-06-15

  According to the present invention (1), an alicyclic diepoxy compound represented by the following general formula (I): can be produced in high purity and high yields at low cost, by epoxidizing the corresponding alicyclic diolefin compound with an organic percarboxylic acid. As the alicyclic diepoxy compound lacks an ester group in the molecule, it will show high reactivity for a cationic catalyst. Besides, when it is used as a curable epoxy resin composition of the present invention (2), it will show an effect of lowering its curing temperature or reducing its curing time. The curable epoxy resin composition has high reactivity for various curing agents, low viscosity, and excellent workability. Moreover, the curable resin composition is also superior in that it has less effect to working surroundings, and a cured product thereof shows useful physical properties for the uses in coatings, ink, adhesives, sealants, encapsulants, and the like. Furthermore, as a resin composition of the present invention (3) shows a low coefficient of water absorption, it is of extremely high quality as an epoxy resin composition for the encapsulation of electronic parts. In addition, a stabilizer for an electrical insulating oil of the present invention (4) (i.e., the alicyclic diepoxy compound or an electrical insulating oil containing such a compound) is low in acid value, and the stabilizer improves the properties of the insulating oil. In addition, a cured product obtained by curing a casting epoxy resin composition for electrical insulation of the present invention (5) has excellent properties such as high bending strength, high Tg, and low permittivity.

  根据本发明(1)，由以下通式(I)代表的脂环族二环氧化合物： 通过将相应的脂环族二烯烃化合物与有机过羧酸进行环氧化反应，可以低成本、高纯度和高产率地生产这种化合物。由于脂环族二环氧化合物分子中缺少酯基，因此对阳离子催化剂的反应活性较高。此外，当它用作本发明的可固化环氧树脂组合物（2）时，会显示出降低固化温度或缩短固化时间的效果。这种可固化环氧树脂组合物对各种固化剂的反应活性高，粘度低，可加工性好。此外，这种可固化树脂组合物还具有对工作环境影响较小的优点，其固化产品在涂料、油墨、粘合剂、密封剂、封装剂等用途中显示出有用的物理性质。此外，由于本发明的树脂组合物（3）的吸水系数较低，因此作为用于电子零件封装的环氧树脂组合物具有极高的品质。此外，本发明的电气绝缘油（4）（即脂环二环氧化合物或含有这种化合物的电气绝缘油）的稳定剂酸值低，稳定剂可改善绝缘油的性能。此外，通过固化本发明用于电气绝缘的浇注环氧树脂组合物（5）得到的固化产品具有优异的性能，例如高弯曲强度、高 Tg 和低介电常数。
• Curable epoxy resin compositions, epoxy resin compositions for the encapsulation of electronic parts, stabilizers for electrical insulating oils, and casting epoxy resin compositions for electrical insulation.
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP2546275A2

  公开（公告）日：2013-01-16

  The present invention provides curable epoxy resin compositions, epoxy resin compositions for the encapsulation of electronic parts, stabilizers for electrical insulating oils, and casting epoxy resin compositions for electrical insulation, characterized by comprising: an alicyclic diepoxy compound represented by the following general formula (I): (wherein, each of R1 to R18, which may be the same or different, represents a hydrogen atom, a halogen atom, a hydrocarbon group that may contain an oxygen atom or a halogen atom, or an alkoxy group that may have a substitutional group).

  本发明提供了可固化环氧树脂组合物、用于封装电子零件的环氧树脂组合物、电气绝缘油的稳定剂以及用于电气绝缘的浇注环氧树脂组合物，其特征在于包括： 由以下通式（I）代表的脂环族二环氧化合物： (其中，R1 至 R18（可以相同或不同）分别代表氢原子、卤素原子、可含有氧原子或卤素原子的烃基、或可含有取代基的烷氧基）。
• Curable composition, adhesive, method of producing fiber-reinforced composite material, and fiber-reinforced composite material
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：EP2930200A1

  公开（公告）日：2015-10-14

  A curable composition is obtained by blending a polymerizable compound (A) having predetermined kinds of polymerizable functional groups, a reactive compound (B) having predetermined kinds of reactive functional groups, a compound (C) which is an imidazolyl group-containing compound having a predetermined structure, and a compound (D) which is an oxime compound or an oxime ester compound having a predetermined structure.

  将具有预定种类可聚合官能团的可聚合化合物 (A)、具有预定种类活性官能团的活性化合物 (B)、具有预定结构的含咪唑基化合物 (C) 和具有预定结构的肟化合物或肟酯化合物 (D) 混合在一起，可得到一种可固化组合物。