1-<(triethylsilyl)oxy>-3-methylcyclohex-1-ene | 18407-91-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1-<(triethylsilyl)oxy>-3-methylcyclohex-1-ene
• 英文别名: triethyl((3-methylcyclohex-1-en-1-yl)oxy)silane；triethyl-(3-methyl-cyclohex-1-enyloxy)-silane；Triaethyl-(3-methyl-cyclohex-1-enyloxy)-silan；Triethyl-(3-methylcyclohexen-1-yl)oxysilane；triethyl-(3-methylcyclohexen-1-yl)oxysilane
• CAS: 18407-91-5
• 化学式: C₁₃H₂₆OSi
• 分子量: 226.434
• InChiKey: MQRLATVOBXDVJB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.71
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  三乙基硅烷 、 3-甲基-2-环己烯-1-酮 在 dihydrogen hexachloroplatinate 、 异丙醇 作用下， 生成 1-<(triethylsilyl)oxy>-3-methylcyclohex-1-ene
  参考文献：
  名称：

  Sadych-Sade; Petrow, Zhurnal Obshchei Khimii, 1959, vol. 29, p. 3194,3196; engl. Ausg. S. 3159, 3160

  摘要：

  DOI：

文献信息

• The synergistic effect of nanoporous AuPd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones
  作者：Qiang Chen、Shinya Tanaka、Takeshi Fujita、Luyang Chen、Taketoshi Minato、Yoshifumi Ishikawa、Mingwei Chen、Naoki Asao、Yoshinori Yamamoto、Tienan Jin

  DOI：10.1039/c3cc49524h

  日期：——

  The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-hydrosilylation of the conjugated cyclic enones with hydrosilane in comparison with the monometallic nanoporous Au and Pd catalysts. The enhanced catalytic properties of AuPdNPore arise mainly from the nanoporous structure and the synergistic effect of the AuPd alloy.

  纳米多孔金钯（AuPdNPore）合金催化剂在共轭环戊烯酮与硅烷的直接1,4-氢硅烷化反应中，相比于单金属纳米多孔金和钯催化剂，表现出更优越的化学选择性和高催化活性。AuPdNPore催化剂的增强催化性能主要源于其纳米多孔结构和金钯合金的协同效应。
• Trimethylstannylvinyl cuprates - - generation and 1, 4 - conjugate addition to α,β - unsaturated ketones
  作者：Oswy Z. Pereira、T.H. Chan

  DOI：10.1016/0040-4039(95)01922-5

  日期：1995.11

  A new convenient route to the bis (trimethylstannylvinyt) cuprate reagent 6 is described. Its addition to α,β- unsaturated ketones has been compared with other mixed cuprates.

  描述了到双（三甲基锡烷基乙烯基）铜酸盐试剂6的新的方便途径。已将其添加到α，β-不饱和酮中与其他混合铜酸盐进行了比较。
• (Trimethylstannyl)vinyl Cuprates:  Generation and Conjugate Addition Reactions
  作者：Oswy Z. Pereira、Tak-Hang Chan

  DOI：10.1021/jo960245n

  日期：1996.1.1

  A new convenient route to the bis[(trimethylstannyl)vinyl] cuprate reagent 9 is described. Its addition to alpha,beta-unsaturated ketones has been studied, Bis(trimethylsilyl)acetamide (BSA) was found to activate 1,4-conjugate addition of 9 to alpha,beta-unsaturated ketone esters without concomitant reduction of the double bond.