1,2-bis(1,5,3-dithiazepan-3-yl)ethane | 1391624-93-3

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫半缩醛胺衍生物
• 英文名称: 1,2-bis(1,5,3-dithiazepan-3-yl)ethane
• 英文别名: 3-[2-(1,5,3-dithiazepan-3-yl)ethyl]-1,5,3-dithiazepane
• CAS: 1391624-93-3
• 化学式: C₁₀H₂₀N₂S₄
• 分子量: 296.546
• InChiKey: MJRSPXRAMHUBNU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  108
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  乙二胺 、 3-(tert-butyl)perhydro-1,5,3-dithiazepine 在 samarium(III) chloride hexahydrate 、 水 作用下， 以 氯仿 为溶剂， 反应 3.5h， 以85%的产率得到1,2-bis(1,5,3-dithiazepan-3-yl)ethane
  参考文献：
  名称：

  以SmCl 3 ·6H 2 O为催化剂合成α，ω-双-1,5,3-二硫杂ze烷的新方法

  摘要：

  对先前未知的α的选择性合成的有效方法，ω -双- 1,5,3-dithiazepinanes基于对氨基转移反应Ñ -叔丁基- 1,5,3-dithiazepinane和再成环反应1-氧杂已经开发了在SmCl 3 ·6H 2 O作为催化剂的情况下与脂肪族二胺形成的3,6-二硫代环庚烷。

  DOI：

  10.1016/j.tetlet.2012.05.161

文献信息

• Synthesis of α,ω-bis-1,5,3-dithiazepanes and their fungicidal properties
  作者：E. B. Rakhimova、R. A. Ismagilov、R. A. Zainullin、N. F. Galimzyanova、A. G. Ibragimov

  DOI：10.1134/s1070427213100066

  日期：2013.10

  A procedure was developed for preparative synthesis of alpha,omega-bis-1,5,3-dithiazepanes by heterocyclization of aliphatic alpha,omega-diamines with N,N,N',N'-tetramethylmethanediamine and 1,2-ethanedithiol. The fungicidal activity of 1,2-bis(1,5,3-dithiazepan-3-yl)ethane and 3,3'-(3,6-dioxaoctane-1,8-diyl)bis-1,5,3-dithiazepane toward microscopic fungi affecting agricultural plants was studied.
• Efficient synthesis of bis(1,5,3-dithiazepanes). Sorption of palladium(II) from nitric acid solutions
  作者：G. R. Khabibullina、T. M. Buslaeva、E. S. Fedotova、V. R. Akhmetova、A. G. Ibragimov

  DOI：10.1134/s1070363217050127

  日期：2017.5

  Bis(1,5,3-dithiazepanes) have been synthesized via cyclocondensation of aliphatic alpha,omega-diamines and hydrazine with formaldehyde and ethane-1,2-dithiol. Palladium(II) sorption with bis(1,5,3-dithiazepanes) from nitric acid solutions has been studied via a static method. Bis(1,5,3-dithiazepanes) efficiently extract palladium(II) from 0.1-4 mol/L nitric acid solutions at room temperature.
• One-pot synthesis of bis-1,5,3-dithiazepanes and their sorption properties toward silver(I) and palladium(II)
  作者：V. R. Akhmetova、G. R. Anpilogova、G. R. Khabibullina、N. S. Akhmadiev、A. G. Ibragimov

  DOI：10.1134/s1070427214050085

  日期：2014.5
• A new method for the synthesis of α,ω-bis-1,5,3-dithiazepinanes using SmCl3·6H2O as the catalyst
  作者：Elena B. Rakhimova、Ekaterina A. Efremova、Ivan S. Bushmarinov、Alexander S. Goloveshkin、Leonard M. Khalilov、Askhat G. Ibragimov、Usein M. Dzhemilev

  DOI：10.1016/j.tetlet.2012.05.161

  日期：2012.8

  An efficient method for the selective synthesis of previously unknown α,ω-bis-1,5,3-dithiazepinanes based on the transamination reaction of N-tert-butyl-1,5,3-dithiazepinane and recyclization reaction of 1-oxa-3,6-dithiacycloheptane with aliphatic diamines in the presence of SmCl3·6H2O as the catalyst, has been developed.

  对先前未知的α的选择性合成的有效方法，ω -双- 1,5,3-dithiazepinanes基于对氨基转移反应Ñ -叔丁基- 1,5,3-dithiazepinane和再成环反应1-氧杂已经开发了在SmCl 3 ·6H 2 O作为催化剂的情况下与脂肪族二胺形成的3,6-二硫代环庚烷。