| 19402-66-5

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 19402-66-5
• 化学式: C8H18LiO
• 分子量: 137.2
• InChiKey: HKIGGNKQCWVRRW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.96
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• PROCESS FOR CONTINUOUSLY PRODUCING (METH)ACRYLIC ESTER POLYMER OR COPOLYMER
  申请人：KURARAY CO., LTD.

  公开号：EP1780222A1

  公开（公告）日：2007-05-02

  A continuous production process, which can allow polymerization to proceed at a milder polymerization temperature and a higher polymerization speed as compared with the conventional method while maintaining a high level of living properties and can produce an (meth)acrylic ester (co)polymer having a narrow molecular weight distribution in a high yield with good productivity. The continuous production process for producing an (meth)acrylic ester (co)polymer comprises the step of continuously feeding an organoaluminum compound-containing polymerization Initiator solution and an (meth)acrylic ester into a reactor to continuously obtain a living polymer- containing polymer reaction liquid. The [molar quantity of methacrylic ester or acrylic ester]/([molar quantity of organoaluminum compound] - [molar quantity of polymerization Initiator])} fed into the reactor is regulated to be 15 to 80, and the content of the (meth)acrylic ester in the total feed amount of a polymerization Initiator solution and an (meth)acrylic ester fed into the reactor is regulated to not more than 5% by mass.

  一种连续生产工艺，与传统方法相比，它可以在较温和的聚合温度和较高的聚合速度下进行聚合，同时保持较高的生活特性，并能以较高的产量和良好的生产率生产出分子量分布较窄的（甲基）丙烯酸酯（共）聚合物。生产(甲基)丙烯酸酯(共)聚合物的连续生产工艺包括以下步骤：将含有机铝化合物的聚合引发剂溶液和(甲基)丙烯酸酯连续加入反应器中，以连续获得含活聚合物的聚合物反应液。注入反应器的[甲基丙烯酸酯或丙烯酸酯摩尔量]/（[有机铝化合物摩尔量]-[聚合引发剂摩尔量]）}调节为 15 至 80，(甲基)丙烯酸酯在注入反应器的聚合引发剂溶液和(甲基)丙烯酸酯总进料量中的含量调节为不超过 5%（按质量计）。
• METHOD OF TAKING (METH)ACRYLIC ESTER POLYMER OUT OF LIQUID REACTION MIXTURE
  申请人：Kuraray Co., Ltd.

  公开号：EP1916262A1

  公开（公告）日：2008-04-30

  PROBLEMS: To easily and efficiently obtain a high quality (meth) acrylate-based polymer containing small residual amount of metal components (an aluminum component, an alkali metal component and other metal components) and having high purity and excellent properties such as heat resistance, transparency and others. MEANS FOR SOLVING THE PROBLEMS: The present invention provides a method of obtaining a (meth)acrylate-based polymer by adding an acid to a reaction solution containing the (meth) acrylate-based polymer obtained by polymerizing a (meth) acrylate-based monomer in a water-insoluble organic solvent in the presence of a metal compound such as a metal-containing polymerization initiator, an organoaluminum compound and the like, washing the reaction solution to which the acid has been added by admixing water at 90°C or more, separating the mixed solution of the reaction solution and water generated by washing into an organic solvent solution layer and an aqueous solution layer, isolating the organic solvent solution separated into a layer, and obtaining the (meth)acrylate-based polymer out of the solution. Also provided is a high-purity (meth)acrylate-based polymer having excellent transparency obtained by the method.

  问题为了简便而有效地获得一种含有少量金属成分（铝成分、碱金属成分和其他金属成分）的高质量（甲基）丙烯酸酯基聚合物，这种聚合物具有高纯度和优异的性能，如耐热性、透明度和其他性能。 解决问题的方法：本发明提供了一种获得(甲基)丙烯酸酯基聚合物的方法，该方法是：在含有(甲基)丙烯酸酯基单体在水不溶性有机溶剂中聚合得到的(甲基)丙烯酸酯基聚合物的反应溶液中加入酸，该反应溶液存在金属化合物，如含金属的聚合引发剂、有机铝化合物等、通过在 90°C 或更高温度下加入水对添加了酸的反应溶液进行洗涤，将反应溶液和洗涤产生的水的混合溶液分离成有机溶剂溶液层和水溶液层，将分离成一层的有机溶剂溶液分离出来，并从溶液中获得(甲基)丙烯酸酯基聚合物。此外，还提供了通过该方法获得的透明度极佳的高纯度（甲基）丙烯酸酯基聚合物。
• ZINC CATALYST / ADDITIVE SYSTEM FOR THE POLYMERIZATION OF EPOXIDE MONOMERS
  申请人：Dow Global Technologies LLC

  公开号：EP3071626A1

  公开（公告）日：2016-09-28
• METHACRYLIC RESIN COMPOSITION AND USE THEREOF
  申请人：Kuraray Co., Ltd.

  公开号：EP3587490B1

  公开（公告）日：2022-10-12
• Process For Continuously Producing (Meth)Acrylic Ester Polymer or Copolymer
  申请人：Hamada Kenichi

  公开号：US20080139759A1

  公开（公告）日：2008-06-12

  A continuous production process, which can allow polymerization to proceed at a milder polymerization temperature and a higher polymerization speed as compared with the conventional method while maintaining a high level of living properties and can produce an (meth)acrylic ester (co)polymer having a narrow molecular weight distribution in a high yield with good productivity. The continuous production process for producing an (meth)acrylic ester (co)polymer comprises the step of continuously feeding an organoaluminum compound-containing polymerization initiator solution and an (meth)acrylic ester into a reactor to continuously obtain a living polymer-containing polymer reaction liquid. The [molar quantity of methacrylic ester or acrylic ester]/([molar quantity of organoaluminum compound]−[molar quantity of polymerization initiator])} fed into the reactor is regulated to be 15 to 80, and the content of the (meth)acrylic ester in the total feed amount of a polymerization initiator solution and an (meth)acrylic ester fed into the reactor is regulated to not more than 5% by mass.