Mass spectrometry of π-complexes of transition metals. XXIII. The ions [C5H5EIV]+ in the gas phase. Synthesis and structure
作者:Yu.S. Nekrasov、V.F. Sizoi、D.V. Zagorevskii、Yu.A. Borisov
DOI:10.1016/s0022-328x(00)81471-0
日期:1981.2
The ions C5HE+ (E = C, Si, Ge, Sn, Pb) were generated in the gas phase. Calculations of the atomization energies confirm their structure as nido-cluster. It is suggested that such ions could be synthesized under normal conditions for all the Group IVA elements, including carbon.
在气相中生成离子C 5 HE +(E = C,Si,Ge,Sn,Pb)。雾化能量的计算证实了其结构为nido团簇。建议可以在正常条件下为包括碳在内的所有IVA族元素合成此类离子。