manganese platinum | 12339-83-2

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: manganese platinum
• 英文别名: platinum manganese；Manganese--platinum (1/1)；manganese;platinum
• CAS: 12339-83-2
• 化学式: MnPt
• 分子量: 250.018
• InChiKey: IGOJMROYPFZEOR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  锰 、 铂 以 neat (no solvent) 为溶剂， 生成 manganese platinum
  参考文献：
  名称：

  高温直接合成量热法测定某些晚期4d和5d过渡金属二元金属间化合物的标准生成焓

  摘要：

  某些晚期 4d 和 5d 过渡金属的金属间化合物的标准形成焓已通过高温直接合成量热法在 1373 +/- 2 K 下进行测量。 报告了以下以 kJ/mol 原子为单位的结果： NbMn(2) (-10.4 +/- 2.7); 铌 (-0.7 +/- 2.8); RhMo (-4.8 +/- 1.8)：PdMn (-45.2 +/- 2.2)；钯（2）钼（-9.2 +/- 1.9）；TaMn(2) (-14.5 +/- 2.5)；IrMn(3) (-13.2 +/- 2.8)：Pt(3)Cr (-8.8 +/- 3.1)；铂锰 (-53.6 +/- 1.5); 铂钼 (-17.9 +/- 2.2); Pt(3)Ta (-21.1 +/- 2.4)；和 YMn(2) (-2.8 +/- 2.8)。将这些值与 Miedema 和同事的预测值以及可用的从头计算的新结果进行比较。我们将展示生成焓如何

  DOI：

  10.1016/j.jallcom.2009.11.092

文献信息

• Intermetallic compound PtMn -derived Pt−MnO supported on mesoporous CeO2: Highly efficient catalysts for the combustion of toluene
  作者：Xiaohang Fu、Yuxi Liu、Jiguang Deng、Lin Jing、Xing Zhang、Kunfeng Zhang、Zhuo Han、Xiyun Jiang、Hongxing Dai

  DOI：10.1016/j.apcata.2020.117509

  日期：2020.4

  possessed good thermal stability and water-resistant performance. Benzyl alcohol, benzoic acid, and maleic anhydride were proven to be the main intermediates of toluene combustion, hence, toluene combustion might take place through a sequence of toluene → benzyl alcohol and benzoic acid → maleic anhydride → carbon dioxide and water, which might obey the Eley―Rideal reaction mechanism. It is concluded

  金属间化合物是非均相催化中的一种重要物质。在这项工作中，我们首先使用聚乙烯吡咯烷酮辅助的乙二醇还原法合成了PtMn y金属间纳米晶体，然后将其负载在源自KIT-6模板路线的介孔CeO 2（meso-CeO 2）的表面， 在空气中500°C煅烧后生成m Pt- n MnO x / meso-CeO 2（m  = 0-0.39 wt％，n = 0-1.21 wt％）催化剂。发现所获得的催化剂表现出有序的介孔结构，表面积为95-108 m 2。/G。0.37Pt-0.16MnO x / meso-CeO 2样品表现出最佳的甲苯燃烧催化性能（在空速= 40,000 mL /（gh）时，T 50％ = 162°C和T 90％ = 171°C）。动力学分析表明，在性能最佳的0.37Pt-0.16MnO x / meso-CeO 2样品上获得的表观活化能（57 kJ / mol）低于在其他样品上获得的表观活化能（63-75
• Pseudogap formation in MnPt and MnPd alloys
  作者：Masato Kubota、Kanta Ono、Rie Y. Umetsu、Hiroyuki Akinaga、Akimasa Sakuma、Kazuaki Fukamichi

  DOI：10.1063/1.2561008

  日期：2007.2.26

  structure of L10-type ordered Mn-based alloys. The effect of disorder on pseudogap formation in Mn1−xPtx (x=0.47, 0.50, 0.51, and 0.54) and Mn1−xPdx (x=0.502, 0.515, and 0.535) alloys has been clarified. The optical reflectivity shows a clear dip around 0.5eV for both MnPt and MnPd alloys, which corresponds to the pseudogap formation. On the other hand, the pseudogap is rather unclear in the other nonequiatomic

  作者进行了光谱分析，以观察 L10 型有序锰基合金的电子结构。无序对 Mn1-xPtx（x=0.47、0.50、0.51 和 0.54）和 Mn1-xPdx（x=0.502、0.515 和 0.535）合金中赝隙形成的影响已得到阐明。对于 MnPt 和 MnPd 合金，光学反射率显示出大约 0.5eV 的明显下降，这对应于假间隙的形成。另一方面，在其他非等原子组成中，赝隙是相当不清楚的。这表明赝隙的形成与锰基合金的有序程度密切相关。
• Structural Changes Induced by Mn Mobility in a Pt_1−xMn_xBinary Composition-Spread Catalyst
  作者：J. E. Harlow、D. A. Stevens、R. J. Sanderson、G. C.-K. Liu、L. B. Lohstreter、G. D. Vernstrom、R. T. Atanasoski、M. K. Debe、J. R. Dahn

  DOI：10.1149/2.019206jes

  日期：——

  The electrochemical behavior of Pt1-xMnx (0.1 < x < 0.8) catalysts prepared by magnetron sputtering were studied extensively using the rotating disk electrode technique, electron microprobe, X-ray photoelectron spectroscopy and X-ray diffraction. The data suggests that Mn forms an oxide layer at the surface of the catalyst upon contact with air. Mn is preferentially drawn out of the intermixed catalyst into the oxide layer, depleting the core of Mn content. Without significant amounts of Mn present at the core of the catalyst, de-alloying reactions have less effect on the electrochemically active surface area compared to the case of Pt1-xNix, for example. High and low Mn content alloys have about the same Pt-area specific current densities, j(specific), so it is likely that all samples have the same catalytic surface composition, namely Pt. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.019206jes] All rights reserved.
• Menshikov, A. Z.; Antropov, V. P.; Gasnikova, G. P., Journal of Magnetism and Magnetic Materials, 1987, vol. 65, p. 159 - 166
  作者：Menshikov, A. Z.、Antropov, V. P.、Gasnikova, G. P.、Dorofeyev, Yu. A.、Kazantsev, V. A.

  DOI：——

  日期：——
• A Partial Phase Diagram of Pt-Rich Pt–Mn Alloys
  作者：Timbangen Sembiring、Miwako Takahashi、Keishin Ota、Toetsu Shishido、Ken-ichi Ohshima

  DOI：10.1143/jpsj.71.2459

  日期：2002.10.15

  We have performed the X-ray and electron diffraction studies to reconstruct a partial phase diagram of Pt-rich Pt-Mn alloys in the composition range of LO to 35 at.% Mn. Electrical resistivity measurement was also used for determining the order-disorder transition temperature in Pt-14.2 at.% Mn alloy. The phase boundary between Cu3Au type and ABC(6) type ordered structures is established, in which the latter has been found recently by the present authors [J. Phys. Soc. Jpn. 71 (2002) 681]. In the ABC(6) type ordered phase, superlattice reflections both at 2 2 2 and its equivalent position (L-point) and at 100, 110 and their equivalent positions (X-point) appear in the composition range from 12.5 to 14.4 at.% Mn below 682 C. In the Cu3Au type ordered phase, diffuse maxima at L-point appear in the composition range from 15.9 to 19.7 at.% Mn in addition to the superlattice reflections at X-point. The Cu3Au type ordered structure is found to be stable in the composition range from 19.7 to 35 at.% Mn without appearing any diffuse scattering at L-point. Furthermore, the phase boundary between Cu3Au type and disordered state is also established.