(2-Ethoxy-4-formylphenyl) 3,5-dinitrobenzoate | 933675-46-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: (2-Ethoxy-4-formylphenyl) 3,5-dinitrobenzoate
• CAS: 933675-46-8
• 化学式: C₁₆H₁₂N₂O₈
• 分子量: 360.28
• InChiKey: OPHSOBPZNDGYGB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  144
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  (2-Ethoxy-4-formylphenyl) 3,5-dinitrobenzoate 、 苯胺 以 甲醇 为溶剂， 反应 0.25h， 以89%的产率得到(E)-2-ethoxy-4-((phenylimino)methyl)phenyl 3,5-dinitrobenzoate
  参考文献：
  名称：

  Synthesis of 3-alkoxy-4-acyloxyphenylmethylene(phenyl)amines

  摘要：

  Previously unknown E isomers of azomethines (Schiff bases) were synthesized from the vanillin and vanillal esters by the reaction with aniline.

  DOI：

  10.1134/s107036320804018x
• 作为产物：
  描述：

  3,5-二硝基苯甲酸 在 吡啶 、 氯化亚砜 作用下， 以 苯 为溶剂， 生成 (2-Ethoxy-4-formylphenyl) 3,5-dinitrobenzoate
  参考文献：
  名称：

  New esters of vanillin and vanillal with some alkane-and arenecarboxylic acids

  摘要：

  Previously unknown esters were synthesized by the reaction of vanillin and vanillal with carboxylic acid chlorides.

  DOI：

  10.1134/s1070427206060322

文献信息

• Synthesis, film-forming properties, and thermal and light sensitivity of N,N′-bis[4-hydroxy(alkoxy, acyloxy)-3-alkoxyphenylmethylidene]benzene-1,4-diamines
  作者：E. A. Dikusar、N. G. Kozlov、V. I. Potkin、V. A. Azarko、A. P. Yuvchenko

  DOI：10.1134/s1070363208020175

  日期：2008.2

  Previously unknown E,E-isomeric Schiff bases were synthesized by reaction of p-phenylenediamine with 4-hydroxy-3-methoxybenzaldehyde, 3-ethoxy-4-hydroxybenzaldehyde, and their O-alkyl and O-acyl derivatives in anhydrous methanol. Film-forming properties and thermal and light sensitivity of the products were studied.

  之前未知的E,E-异构Schiff碱是通过在无水甲醇中将对苯二胺与4-羟基-3-甲氧基苯甲醛、3-乙氧基-4-羟基苯甲醛及其O-烷基和O-酰基衍生物反应合成的。对产物的成膜性能以及热稳定性和光敏感性进行了研究。
• Synthesis of (E)-N-(3-alkoxy-4-acyloxyphenylmethylene)-N-(e-cyclohexyl)amines
  作者：E. A. Dikusar、N. G. Kozlov、V. I. Potkin

  DOI：10.1134/s1070363208060169

  日期：2008.6

  Previously unknown E isomers of azornethines (Schiff bases) were synthesized from vanillin and vanillin esters by their reaction wit-i cyclohexylarnine.
• 2-[3-Alkoxy-4-(hydroxy, alkoxy, acyloxy)phenyl]-2,3-dihydro-1H-benzimidazoles on the basis of vanillin and vanillal derivatives
  作者：E. A. Dikusar、N. G. Kozlov、V. I. Potkin

  DOI：10.1134/s1070363207110138

  日期：2007.11

  Previously unknown 2-[3-alkoxy-4-(hydroxy, alkoxy, acyloxy)phenyl]-2,3-dihydro-1H-benzimidazoles were prepared by the reaction of aldehydes of the vanillin series and their ethers and esters with 1,2-phenylenediamine in absolute methanol.
• Synthesis and study of film-forming properties and light sensitivity of 4-acyloxy-3-methoxy(ethoxy)phenylmethylidene-(chrysen-2-yl)amines
  作者：E. A. Dikusar、N. G. Kozlov、V. I. Potkin、V. A. Azarko、A. P. Yuvchenko

  DOI：10.1134/s1070363207020144

  日期：2007.2

  Reactions of chrysen-2-amine with esters derived from vanillin and vanillal in methanol gave previously unknown Schiff bases of the chrysene series as E isomers, and their film-forming and light-sensitive properties were examined.
• Synthesis of N,N′-bis-[3-alkoxy-4-(hydroxy, alkoxy, acyloxy)-phenylmethylene- and -Phenylmethyl]-1,3-phenylenediamines
  作者：E. A. Dikusar、V. I. Potkin、N. G. Kozlov、A. P. Yuvchenko

  DOI：10.1134/s1070363209020157

  日期：2009.2

  Starting with the vanillin series aldehydes, by reaction with 1,3-phenylenediamine in absolute methanol E,E-N,N'-bis-[3-alkoxy-4-(hydroxy-, alkoxy-, acyloxy)phenylme-thylene]-1,3-phenyl-enediamines (Shiff bases) are synthesized from reduction with Na[BH(OAc)(3)] in benzene were prepared respective N,N'-bis-[3-alkoxy-4-(hydroxy-, alkoxy-, acyloxy)phenylmethyl]-1,3-phenyl-enediamines.