diamminedinitritoplatinum(II) | 63718-03-6

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 英文名称: diamminedinitritoplatinum(II)
• 英文别名: diamminedinitritoplatinum；Pt(NO2)2(NH3)2；azane;platinum(2+);dinitrite
• CAS: 63718-03-6
• 化学式: H₆N₄O₄Pt
• 分子量: 321.152
• InChiKey: FAOUENTVTAXLPG-UHFFFAOYSA-L

物化性质

• 物理描述：
  Liquid

计算性质

• 辛醇/水分配系数(LogP)：
  0.82
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  107
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  硫酸钴水合物 、 diamminedinitritoplatinum(II) 在 Na₂CO₃ 、 NaCH₃CO₂ 、 C₆H₁₅NO₃ 作用下， 以 硫酸 、 水 为溶剂， 生成 cobalt platinum
  参考文献：
  名称：

  Co[sub x]Pt[sub 1−x]薄膜的电沉积

  摘要：

  We show that single-phase face-centered cubic (fcc) CoxPt1-x can be electrodeposited from solution containing cobalt(II)sulfate and diamminedinitritoplatinum(II). The composition and crystal structure of the films are dependent on solution composition and deposition potential. For films deposited at constant current, the film composition is only weakly dependent on the Co(II)/Pt(II) ratio. However, the film composition is strongly dependent on the deposition potential. At intermediate potentials, films with a mole fraction of cobalt up to x = 0.52 are single-phase fcc CoxPt1-x solid solutions. At more negative deposition potentials phase separation leads to the formation of a two-phase alloy with disordered hexagonal close-packed CoxPt1-x and fcc CoxPt1-x solid solutions. (C) 2004 The Electrochemical Society.

  DOI：

  10.1149/1.1836128

文献信息

• Electrodeposition of Co–Pt continuous films and nanowires within diblock copolymer template
  作者：M.S. Khatri、H. Schlörb、S. Fähler、L. Schultz、B. Nandan、M. Böhme、R. Krenek、M. Stamm

  DOI：10.1016/j.electacta.2008.05.029

  日期：2009.3

  Patterned media for future ultrahigh-density magnetic data storage can be prepared by electrodeposition into ordered arrays of nanostructured templates. Diblock copolymer templates have been proposed as a promising alternative to alumina templates. They possess smaller feature sizes than alumina and thereby allow for higher storage densities. Templates with pore diameters of similar to 8 nm have been fabricated by dipcoating a conducting substrate into a solution of polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) and 2-(4'-hydroxybenzeneazo) benzoic acid (HABA). A vapor annealing step was interposed for better ordering. The pores are opened by dissolving the HABA from the supramolecular assembly and afterwards filled by electrodeposition.Fe-Pt and Co-Pt alloys are the materials of choice for filling the pores due to their hard magnetic properties like high coercivity and anisotropy. Co-rich Co80Pt20 was chosen for this study because it does not require post annealing as in the case of ordered L1(0) CoPt or FePt. Continuous films have been deposited in order to identify the optimum deposition conditions and the influence of deposition current density on chemical composition, growth morphology, and structural and magnetic properties has been studied systematically. The first results on templates electrochemically filled with Co-Pt are presented together with an analysis of their magnetic properties. (C) 2008 Elsevier Ltd. All rights reserved.
• Zeligovskaya, N. N.; Chernova, N. A.; Kileev, R. G., Koordinatsionnaya Khimiya, 1983, vol. 9, p. 380 - 387
  作者：Zeligovskaya, N. N.、Chernova, N. A.、Kileev, R. G.、Spitsyn, V. I.

  DOI：——

  日期：——
• Electrodeposition of Co[sub x]Pt[sub 1−x] Thin Films
  作者：Tom S. Eagleton、Jeremy Mallet、Xuemei Cheng、Judy Wang、Chia-Ling Chien、Peter C. Searson

  DOI：10.1149/1.1836128

  日期：——

  We show that single-phase face-centered cubic (fcc) CoxPt1-x can be electrodeposited from solution containing cobalt(II)sulfate and diamminedinitritoplatinum(II). The composition and crystal structure of the films are dependent on solution composition and deposition potential. For films deposited at constant current, the film composition is only weakly dependent on the Co(II)/Pt(II) ratio. However, the film composition is strongly dependent on the deposition potential. At intermediate potentials, films with a mole fraction of cobalt up to x = 0.52 are single-phase fcc CoxPt1-x solid solutions. At more negative deposition potentials phase separation leads to the formation of a two-phase alloy with disordered hexagonal close-packed CoxPt1-x and fcc CoxPt1-x solid solutions. (C) 2004 The Electrochemical Society.