bis(N,N-diethyldithiocarbamato)diiodotin | 20190-60-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: bis(N,N-diethyldithiocarbamato)diiodotin
• 英文别名: N,N-diethylcarbamodithioate;diiodotin(2+)
• CAS: 20190-60-7；34843-33-9；38255-55-9；17568-94-4
• 化学式: C₁₀H₂₀I₂N₂S₄Sn
• 分子量: 669.065
• InChiKey: VRNSKBKKHMLHNZ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  5.01
• 重原子数：
  19
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  121
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  碘化锡 、 二乙基二硫代氨基甲酸二乙铵盐 以 乙醇 、 氯仿 为溶剂， 以74%的产率得到bis(N,N-diethyldithiocarbamato)diiodotin
  参考文献：
  名称：

  Jalil, N. S. Neelam, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1989, vol. 19, p. 1069 - 1084

  摘要：

  DOI：

文献信息

• COORDINATION COMPOUNDS OF TIN AND BISMUTH. COMPLEXES OF TIN(IV) AND BISMUTH(III) WITH N,N-DIALKYLDITHIOCARBAMATES
  作者：I. A. Mustafa、Amer A. Taqa

  DOI：10.1081/sim-100104783

  日期：2001.4.30

  Tin and bismuth metals react with N,N,N,N'-tetraethylthiuramdisulfide, [Et2NC(S)S](2), and N,N,N',N'-tetramcthylthiuramdisulfide, [Mt(2)NC(S)S](2), in refluxing toluene to give the compounds Sn(S2CNR2)(4) (R=Et, Me) in high yield. Under similar conditions bismuth gives Bi(S2CNR2)(3). The reaction of metallic tin with a mixture of iodine and [R2NC(S)S](2) gives the compounds SnI(S2CNR2)(3) and SnI2(S2CNR2)(2). Similarly, with mixtures of [R2NC(S)S](2) and I-2, bismuth yields BiI(S2CNR2)(2) and BiI2(S2CNR2). Adducts of Bi(S2CNR2)(3) with 1,10-phenanthroline and 2.2'-bipyridyl were also prepared. The compounds and adducts were characterized by microanalyses, infrared, UV/Visible spectroscopy and conductivity measurements.
• Jalil, N. S. Neelam, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1989, vol. 19, p. 1069 - 1084
  作者：Jalil, N. S. Neelam

  DOI：——

  日期：——