copper N,N'-diethyldithiocarbamate

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: copper N,N'-diethyldithiocarbamate
• 英文别名: N,N-Diethyldithiocarbamat-Kupfer；copper diethyldithiocarbamate；copper(I) diethyldithiocarbamate；diethyl-dithiocarbamic acid ; copper (I)-salt；Diaethyl-dithiocarbamidsaeure; Kupfer(I)-Salz；Diaethyl-dithiocarbamidsaeure; Kupfersalz；Cu(Et2dtc)；copper(1+);N,N-diethylcarbamodithioate
• 化学式: C₅H₁₀NS₂*Cu
• 分子量: 211.819
• InChiKey: VXYNPJHDOZAJNS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.16
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  36.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  copper N,N'-diethyldithiocarbamate 在 氧气 作用下， 以 not given 为溶剂， 生成 copper diethyldithiocarbamate 、 copper diethyldithiocarbamate
  参考文献：
  名称：

  Strizhakova, N. G.; Meletin, Yu. A.; Travin, S. O., Koordinatsionnaya Khimiya, 1988, vol. 14, p. 417 - 423

  摘要：

  DOI：
• 作为产物：
  描述：

  二硫化四乙基秋兰姆 在 铜 作用下， 生成 copper N,N'-diethyldithiocarbamate
  参考文献：
  名称：

  Fredga, Recueil des Travaux Chimiques des Pays-Bas, 1950, vol. 69, p. 416,420

  摘要：

  DOI：

文献信息

• Coinage Metal Complexes of Tris(pyrazolyl)methanide-Based Redox-Active Metalloligands
  作者：Sandra González-Gallardo、Istemi Kuzu、Pascual Oña-Burgos、Tanja Wolfer、Cong Wang、Karl W. Klinkhammer、Wim Klopper、Stefan Bräse、Frank Breher

  DOI：10.1021/om4010498

  日期：2014.2.24

  expected, both complexes act as κ1C ligands toward coinage metal fragments to yield dinuclear complexes of the general formula [RuCpX(μ-Tpmd)MX}] (μ-Tpmd = μ-κ1C:κ3N-[C(pz)3]; M = Au, X = Cl, CpX = C5H5 (3a) or C5Me5 (3b); M = Au, X = CN, CpX = C5H5 (4a) or C5Me5 (4b); M = Cu, X = OC(O)Me, CpX = C5H5 (5a); M = Cu, X = Si(SiMe3)3, CpX = C5H5 (6a) or C5Me5 (6b); M = Ag, X = SC(S)NEt2, CpX = C5H5 (7a)

  一系列含有氧化还原活性metalloligands货币金属配合物[RuCp X（κ 3 Ñ -Tpmd）] κ 3 Ñ -Tpmd =κ 3 ñ - [C（PZ）3 ]与PZ =吡唑基; [RuCp（TPMD）]（2A）和[RuCp *（TPMD）]（2B）}被呈现。图2a和图2b是可分离的，相对稳定的化合物，尽管它们在κ的桥头位置设有一个“裸”碳负离子3 Ñ配位的三（吡唑基）甲烷化配体支架。正如预期的那样，二者的复合物作为κ 1个Ç朝向硬币金属片段的配体，以产生通式[RuCp的双核配合物X（μ-TPMD）MX}]（μ-TPMD =μ-κ 1 Ç：κ 3 ñ - [C（PZ）3 ]; M =的Au，X =氯中，Cp X = C 5 H ^ 5（图3a）或C 5我5（图3b）; M =金，X = CN中，Cp X = C 5 H ^ 5（图4a）或C 5我5（4b中）; M =铜，X =
• Chromium(VI) nitrido complexes: reactions with Brønsted acids and synthesis of organometallic derivatives
  作者：Aaron L. Odom、Christopher C. Cummins

  DOI：10.1016/s0277-5387(97)00402-6

  日期：1998.3

  Abstract The chromium(VI) nitrido complex NCr(N- i -Pr 2 ) 3 was prepared in 67% yield by vanadium(III)-mediated deoxygenation of coordinated nitric oxide. The iodide complex NCr(I)(N- i -Pr 2 ) 2 . prepared by treatment of NCr(N- i -Pr 2 ) 3 with lutidinium iodide, was coverted to NCr(CH 2 SiPhMe 2 )(N- i -Pr 2 ) 2 upon treatment with Mg(CH 2 SiPhMe 2 ) 2 . NCr(N- i -Pr 2 ) 3 reacts with 1 equiv.

  摘要通过钒（III）介导的配位一氧化氮的脱氧反应，以67％的收率制备了亚硝酸铬（VI）络合物NCr（N-i-Pr 2）3。碘化物络合物NCr（I）（N-i-Pr 2）2。通过用碘化lut处理NCr（N-i-Pr 2）3制备的化合物在用Mg（CH 2 SiPhMe 2）2处理后被掩盖为NCr（CH 2 SiPhMe 2）（N-i-Pr 2）2。NCr（N i -Pr 2）3与1当量反应。苯酚或HOC（CF 3）2 Me生成一元醇盐配合物NCr（OPh）（N-i-Pr 2）2）2或NCr（OC（CF 3）2 Me）（N- i -Pr 2 ）2，分别的收益率是89％和77％。在NCr（OC（CF 3）2 Me）（N-i-Pr 2）2上进行的自旋饱和转移测量表明CrN酰胺键旋转的一级速率常数约为13 s -1。在NCr（N-i-Pr 2）3中添加过量的HOC（CF 3）2 Me可以在86中生成单酰胺基复合物NCr（OC（CF
• Convenient synthesis of copper (I) thiolates and related compounds
  作者：Lynda M. Nguyen、Megan E. Dellinger、Jeffrey T. Lee、Ronald A. Quinlan、Arnold L. Rheingold、Robert D. Pike

  DOI：10.1016/j.ica.2004.11.030

  日期：2005.3

  Copper (I) salts of various anions including thiolates, diethyl dithiocarbamate, diethyl dithiophosphate, trithiocyanurate, 1cyano-3-methylisothiourea, 2-aminothiazole, and tetrakis(1-imidazolyl)borate are conveniently synthesized by reducing copper (II) sulfate in aqueous ammonia. The addition of phosphine ligands to several of the products is demonstrated, and the crystal structure of [Cu2(MBT)2(DPPE)3]

  通过在氨水中还原硫酸铜（II）可以方便地合成各种阴离子的铜（I）盐，包括硫醇盐，二乙基二硫代氨基甲酸酯，二乙基二硫代磷酸酯，三硫氰尿酸酯，1-氰基-3-甲基异硫脲，2-氨基噻唑和四（1-咪唑基）硼酸酯。 。证明了将膦配体添加到几种产品中，并证明了[Cu2（MBT）2（DPPE）3] AE Et2O的晶体结构（MBT = 2-巯基苯并噻唑酸盐，DPPE = 1,2-双（二苯基膦基）乙烷）被报道。 2004 Elsevier BV保留所有权利。
• Synthesis, Crystal Structures, Magnetic Properties and Photoconductivity of C ₆₀ and C ₇₀ Complexes with Metal Dialkyldithiocarbamates M(R ₂ dtc) <i> _x </i> , where M = Cu ^II , Cu ^I , Ag ^I , Zn ^II , Cd ^II , Hg ^II , Mn ^II , Ni ^II , and Pt ^II ; R = Me, Et, and <i>n</i> Pr
  作者：Dmitri V. Konarev、Andrey Y. Kovalevsky、Salavat S. Khasanov、Gunzi Saito、Dmitri V. Lopatin、Alexey V. Umrikhin、Akihiro Otsuka、Rimma N. Lyubovskaya

  DOI：10.1002/ejic.200501110

  日期：2006.5

  New complexes of fullerenes C 60 and C 70 with metal dialkyldithiocarbamates, [M(R 2 dtc) x ]·[C 60 ( 70 )]·[Solvent], R = Et [M = Cu II (C 60 , 1; C 70 , 2), Cu I (C 60 , 3; C 70 , 4), Ag I (C 60 , 5), Zn II (C 60 , 6), Cd II (C 60 , 7; C 70 , 8), Hg II (C 60 , 9), Mn II (C 70 , 10)], R = Et and Me [M = Cu II (C 60 , 11), and Zn II (C 60 , 12)], and R = nPr [M = Cu II (C 60 , 13), Ni II (C 60 , 14)

  富勒烯 C 60 和 C 70 与金属二烷基二硫代氨基甲酸盐的新配合物，[M(R 2 dtc) x ]·[C 60 ( 70 )]·[溶剂]，R = Et [M = Cu II (C 60 , 1; C 70, 2), Cu I (C 60, 3; C 70, 4), Ag I (C 60, 5), Zn II (C 60, 6), Cd II (C 60, 7; C 70, 8) , Hg II (C 60 , 9), Mn II (C 70, 10)], R = Et and Me [M = Cu II (C 60, 11), and Zn II (C 60, 12)], and R得到=nPr[M=Cu II (C 60, 13), Ni II (C 60, 14), 和Pt II (C 60, 15)]。M(R 2 dtc) x 与作为四面体单体 (6, 12)、二聚体 (1, 7
• Bright Red Luminescence from Ag–In–Ga–S-Based Quantum Dots with the Introduction of Copper
  作者：Taro Uematsu、Navapat Krobkrong、Kenichiro Asai、Genichi Motomura、Yoshihide Fujisaki、Tsukasa Torimoto、Susumu Kuwabata

  DOI：10.1246/bcsj.20230216

  日期：2023.11.15

  This study presents cadmium-free, red-emission quantum dots (QDs) synthesized by incorporating Cu into silver indium gallium sulfide/gallium sulfide (Ag–In–Ga–S/Ga–S) core/shell QDs. By using a previous technique, in which the original Ag–In–Ga–S/Ga–S core/shell QDs exhibiting band-edge photoluminescence (PL) were improved to achieve a narrower emission and facile synthesis, we injected a mixture of Cu and Ag sources into a heated solution containing In, Ga, and S sources. This resulted in the formation of Ag–Cu–In–Ga–S quinary QDs without any precipitation. After being coated with a Ga–S shell, these QDs exhibit a red PL with a spectral full-width at half maximum of 55–60 nm. Although the PL wavelength was responsive to changes in In/Ga ratios, it was unaffected by variations in Cu/Ag ratios due to the transition between conduction band electrons and holes localized at Cu cites. Notably, the electroluminescence device exhibited high-purity red light that satisfies the recommendation ITU-R BT.2020 standard.

  摘要 本研究介绍了在银铟硫化镓/硫化镓（Ag-In-Ga-S/Ga-S）核/壳量子点（QDs）中加入铜而合成的无镉、红光发射量子点（QDs）。通过使用以前的技术，我们将铜源和银源的混合物注入到含有In、Ga和S源的加热溶液中，从而形成了Ag-Cu-Ga-S/Ga-S核/壳QDs。这样就形成了没有任何沉淀的 Ag-Cu-In-Ga-S 二元 QDs。在镀上 Ga-S 外壳后，这些 QDs 显示出红色的 PL，光谱半最大全宽为 55-60 nm。虽然光致发光波长对 In/Ga 比率的变化有反应，但由于导带电子和空穴在铜引线上的转换，光致发光波长不受 Cu/Ag 比率变化的影响。值得注意的是，该电致发光器件发出的高纯度红光符合建议的 ITU-R BT.2020 标准。