trimethylsilyloxy-nonane | 18388-84-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: trimethylsilyloxy-nonane
• 英文别名: trimethyl-nonyloxy-silane；Trimethyl-nonyloxy-silan；Trimethyl-n-nonoxysilan；Trimethylsiloxy-n-nonan；Silane, trimethyl(nonyloxy)-；trimethyl(nonoxy)silane
• CAS: 18388-84-6
• 化学式: C₁₂H₂₈OSi
• 分子量: 216.439
• InChiKey: WZNQZZJRYURJIJ-UHFFFAOYSA-N

物化性质

• 保留指数：
  1265;1270;1278.3

计算性质

• 辛醇/水分配系数(LogP)：
  4.59
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  trimethylsilyloxy-nonane 在 ammonium cerium(IV) nitrate 、 HZSM-5 zeolite 作用下， 以 水 为溶剂， 反应 0.13h， 以91%的产率得到壬醛
  参考文献：
  名称：

  Oskooie, Hossein A.; Amiri, Somaih Solemani; Heravi, Majid M., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2006, vol. 45, # 3, p. 813 - 814

  摘要：

  DOI：
• 作为产物：
  描述：

  六甲基二硅氮烷 、 1-壬醇 生成 trimethylsilyloxy-nonane
  参考文献：
  名称：

  Consensus Among Economists: Revisited

  摘要：

  The authors explore consensus among economists on specific propositions on the basis of a fall 2000 survey of American Economic Association members. Because some propositions are drawn from earlier studies, the results illustrate the dynamics of opinion within the profession. The authors generally find consensus within the profession, although the degree of consensus varies between propositions that are international, macroeconomic, and microeconomic in nature. Consensus is particularly strong for propositions of free international trade and capital flows. In contrast, macroeconomic propositions exhibit a lower degree of consensus, partly because of increased agreement with monetarist and supply-side propositions over time. The profession displays substantial skepticism concerning claims of the "New Economy.".

  DOI：

  10.1080/00220480309595230

文献信息

• Synthesis methods and reactions. 71. Chlorotrimethylsilane and tert-butyl dimethylsilyl chloride/lithium sulfide, mild and efficient silylating reagents
  作者：George A. Olah、B. G. Balaram Gupta、Subhash C. Narang、Ripudaman Malhotra

  DOI：10.1021/jo01338a011

  日期：1979.11
• Magnesium Hydrogensulfate [Mg(HSO₄)₂] as an Efficient Catalyst for the Preparation of Silyl Ethers, Dibenzo[a,j]xanthenes, and Octahydroxanthene Derivatives
  作者：Hamid Reza Shaterian、Razieh Doostmohammadi、Fahimeh Khorami、Majid Ghashang

  DOI：10.1080/10426500902758329

  日期：2009.12.29

  Magnesium hydrogensulfate [Mg(HSO4)(2)], as a heterogeneous solid acid catalyst, has been used for the mild formation of trimethylsilyl (TMS) ethers from various primary, secondary, and tertiary aliphatic alcohols; aromatic alcohols; and oximes using hexamethyldisilazane (HMDS) under ambient conditions. In addition, 14-aryl-14H-dibenzo[a,j]xanthenes and 1,8-dioxo- octahydroxanthene derivatives were synthesized in the presence of Mg(HSO4)(2) with short reaction times in high to excellent yield under solvent-free conditions.
• Pola,J. et al., Collection of Czechoslovak Chemical Communications, 1974, vol. 39, p. 3705 - 3710
  作者：Pola,J. et al.

  DOI：——

  日期：——
• Woronkow; Schabarowa, Zhurnal Obshchei Khimii, 1959, vol. 29, p. 1528,1530;engl.Ausg.S.1501,1503
  作者：Woronkow、Schabarowa

  DOI：——

  日期：——
• Krolevets, A. A.; Antipova, V. V.; Popov, A. G., Journal of general chemistry of the USSR, 1988, vol. 58, # 10, p. 2023 - 2030
  作者：Krolevets, A. A.、Antipova, V. V.、Popov, A. G.、Adamov, A. V.

  DOI：——

  日期：——

表征谱图